Browsing by Author "Beobide, Garikoitz"
Now showing items 1-20 of 29
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A metal-organic framework based on Co(II) and 3-aminoisonicotinate showing specific and reversible colourimetric response to solvent exchange with variable magnet behaviour
Pajuelo Corral, Oier; Pérez Yáñez, Sonia ; Vitorica Yrezabal, Iñigo J.; Beobide Pacheco, Garikoitz ; Zabala Lekuona, Andoni; Rodríguez Diéguez, Antonio; Seco Botana, José Manuel ; Cepeda Ruiz, Javier (Elsevier, 2022-06)[EN] A versatile metal-organic system consisting of Co-based compounds that show reversible transformations between a 3D metal-organic framework (MOF) of {[Co(mu-3isoani)(2)]center dot DMF}(n) (1) formula (where 3isoani - ... -
A straightforward route to obtain zirconium based metal-organic gel
Santos-Lorenzo, Janire; San José-Velado, Rubén; Albo, Jonathan; Beobide Pacheco, Garikoitz ; Castaño Sánchez, Pedro; Castillo García, Oscar ; Luque Arrebola, Antonio ; Pérez Yáñez, Sonia (Elsevier, 2019-04-12)Zirconium based metal-organic gels are obtained through a rapid method at room temperature, employing green solvents, in which the role of water is important. These porous materials, decorated with Brønsted acid sites, ... -
Adenine nucleobase directed supramolecular architectures based on ferrimagnetic heptanuclear copper(II) entities and benzenecarboxylate anions
Pascual Colino, Jon ; Beobide Pacheco, Garikoitz ; Castillo García, Oscar ; Lodewyckx, Peter; Luque Arrebola, Antonio ; Pérez Yáñez, Sonia ; Román Polo, Pascual ; F. Velasco, Leticia (Elsevier, 2019-10-05)Two planar organic anions, benzoate and benzene-1,4-dicarboxylate (terephthalate), have been selected as potential π-stacking intercalators among ferrimagnetic [Cu7(μ-adeninato)6(μ3-OH)6(μ-H2O)6]2+ heptameric discrete ... -
Aerogels of 1D Coordination Polymers: From a Non-Porous Metal-Organic Crystal Structure to a Highly Porous Material
Angulo Ibáñez, Adrián; Beobide Pacheco, Garikoitz ; Castillo García, Oscar ; Luque Arrebola, Antonio ; Pérez Yáñez, Sonia ; Vallejo Sánchez, Daniel (MDPI, 2016-01-15)The processing of an originally non- porous 1D coordination polymer as monolithic gel, xerogel and aerogel is reported as an alternative method to obtain novel metal- organic porous materials, conceptually different to ... -
An in solution adsorption characterization technique based on the response to an external magnetic field of porous paramagnetic materials: application on supramolecular metal–adenine frameworks containing heterometallic heptameric clusters
Pascual Colino, Jon ; Pérez Aguirre, Rubén; Beobide Pacheco, Garikoitz ; Castillo García, Oscar ; De Pedro del Valle, Imanol; Luque Arrebola, Antonio ; Mena Gutiérrez, Sandra; Pérez Yáñez, Sonia (Royal Society of Chemistry, 2023-01-18)Herein we explore the opportunities arising from combining magnetic properties and porosity in metal–organic materials. In this sense, we have prepared an adenine based homometallic wheel-shaped heptameric [Cu7(μ-adenina ... -
Base nitrogenatuak konposatu metal-organiko porotsuak eraikitzeko baliabide: zenbait adibide
Pérez Yáñez, Sonia ; Beobide Pacheco, Garikoitz ; Castillo García, Oscar ; Cepeda Ruiz, Javier; Luque Arrebola, Antonio ; Román Polo, Pascual (Servicio Editorial de la Universidad del País Vasco/Euskal Herriko Unibertsitatearen Argitalpen Zerbitzua, 2017)Metal-organic frameworks (MOFs) and supramolecular metal-organic frameworks (SMOFs) are porous crystalline materials which have become a very sub-stantial field of research over the last years. These materials consist of ... -
Consecutive Single-Crystal-to-Single-Crystal Isomerization of Novel Octamolybdate Anions within a Microporous Hybrid Framework with Robust Water Sorption Properties
Ruiz Bilbao, Estibaliz; Iturrospe Ibarra, Amaia; Reinoso, Santiago; Artetxe Arretxe, Beñat; Beobide Pacheco, Garikoitz ; San Felices Mateos, Leire ; Lezama Diago, Luis María; Gutiérrez Zorrilla López, Juan Manuel ; Sensharma, Debobroto; Zaworotko, Michael J. (Wiley, 2023-10)The 3D hybrid framework [{Cu(cyclam)}3(κ-Mo8O27)] ⋅ 14H2O (1) (cyclam=1,4,8,11-tetraazacyclotetradecane) undergoes sequential single-crystal-to-single-crystal transformations upon heating to afford two different anhydrous ... -
Coordination compounds of organosulfur ligands as precursors of nanostructured materials.
Vallejo Sánchez, Daniel (2017-07-18)This work presents the synthesis and characterization of a series of coordination compounds based on metal(II)-organosulfur complexes as precursors of zero- and three-dimensional nanomaterials.On the one hand, thiocarboxylato ... -
Copper(II) invigorated EHU-30 for continuous electroreduction of CO2 into value-added chemicals
Landaluce Álvarez, Nerea; Perfecto Irigaray, Maite; Albo, Jonathan; Beobide Pacheco, Garikoitz ; Castillo García, Oscar ; Irabien, Angel; Luque Arrebola, Antonio ; Méndez, Alba S. J.; Platero-Prats, Ana E.; Pérez Yáñez, Sonia (Nature, 2022-05-20)The doping of zirconium based EHU-30 and EHU-30-NH2 metal-organic frameworks with copper(II) yielded a homogeneous distribution of the dopant with a copper/zirconium ratio of 0.04-0.05. The doping mechanism is analysed by ... -
Copper(II)-porphyrin functionalized titanium(IV) metal-organic aerogels for the visible-light driven conversion of CO2 to alcohols
Perfecto Irigaray, Maite; Merino García, Ivan; Albo Sánchez, Jonathan; Beobide Pacheco, Garikoitz ; Castillo García, Oscar ; Luque Arrebola, Antonio ; Pérez Yáñez, Sonia (Elsevier, 2023-08)This manuscript covers the synthesis and characterization of a series of titanium based metal-organic aerogels (MOAs) functionalized with copper(II)-metalated porphyrins for their application in visible-light-driven carbon ... -
Desarrollo de materiales fotocatalíticos mediante formulaciones sol-gel y estructuras metal-orgánicas de Ti(IV) para su aplicación en la degradación de materia orgánica y reducción de CO2
Angulo Ibáñez, Adrián (2022-10-21)El crecimiento económico de la sociedad cada vez tiene un mayor impacto en la degradación del medio ambiente, uno de los principales problemas para la humanidad. Este crecimiento conlleva un incremento en la producción y ... -
Fabrication and optimization of perovskite-based photoanodes for solar-driven CO2 photoelectroreduction to formate
Abarca, José Antonio; Merino García, Iván; Díaz Sainz, Guillermo; Perfecto Irigaray, Maite; Beobide Pacheco, Garikoitz ; Irabien, Angel; Albo Sánchez, Jonathan (Elsevier, 2024)The photoelectrochemical reduction of CO2 to value-added products represents a promising strategy for mitigating CO2 emissions. However, further research efforts need to be undertaken to enable the technology for scale-up, ... -
Ferromagnetic supramolecular metal-organic frameworks for active capture and magnetic sensing of emerging drug pollutants
Pérez Aguirre, Rubén; Artetxe Arretxe, Beñat; Beobide Pacheco, Garikoitz ; Castillo García, Oscar ; De Pedro, Imanol; Luque Arrebola, Antonio ; Pérez Yáñez, Sonia ; Wuttke, Stefan (Elsevier ; Cell Press, 2021-05-19)[EN] Capture and sensing of emerging pollutants is one of the increasing environmental concerns due to the adverse ecological and human health effects. Here, we report the synthesis of a supramolecular metal-organic framework ... -
Gai naiz kimikari baten zereginik oinarrizkoenetakoa gauzatzeko: materia eta bere izaera ezagutu, bere erreaktibotasuna eta propietateak arakatuz?
Azken urteotan zehar, kimika ez-organikoa saiakuntza praktikoen bidez irakasteko ohiko modua, praktika-gidoiak ematea izan da, bertan jarraitu beharreko prozedura ongi zehaztuta egonik eta ikasleak jarraitzeko erraza izanik, ... -
Incommensurate crystal structure, thermal expansion study and magnetic properties of (dimethylimidazolium)2[Fe2Cl6(μ-O)]
Scé, Fabio; González Izquierdo, Palmerina; Cano, Israel; Beobide Pacheco, Garikoitz ; Fabelo, Oscar; Vieira, Bruno J C; Waerenborgh, João C; Vallcorba, Oriol; Castillo García, Oscar ; De Pedro, Imanol (IOP, 2020-01-01)A thorough characterization of the title compound, (dimim)(2)[Fe2Cl6(mu-O)], consisting of a (mu-oxido)-bridged binuclear iron(III) complex and 1,3-dimethylimiazolium (dimim) cation, has been performed using a wide range ... -
Innovative Microstructural Transformation upon CO2 Supercritical Conditions on Metal-Nucleobase Aerogel and Its Use as Effective Filler for HPLC Biomolecules Separation
Maldonado, Noelia; Beobide Pacheco, Garikoitz ; Reyes Martín, Efraim; Martínez, José Ignacio; Gómez-García, Carlos J.; Castillo García, Oscar ; Amo-Ochoa, Pilar (MDPI, 2022-02-17)This work contributes to enlightening the opportunities of the anisotropic scheme of non-covalent interactions present in supramolecular materials. It provides a top-down approach based on their selective disruption that ... -
Isoreticular chemistry and applications of supramolecularly assembled copper−adenine porous materials
Mena Gutiérrez, Sandra; Pascual Colino, Jon ; Beobide Pacheco, Garikoitz ; Castillo García, Oscar ; Castellanos Rubio, Ainara; Luque Arrebola, Antonio ; Maiza Razkin, Ekain; Mentxaka Salgado, Jon; Pérez Yáñez, Sonia (American Chemical Society, 2023-11-01)The useful concepts of reticular chemistry, rigid and predictable metal nodes together with strong and manageable covalent interactions between metal centers and organic linkers, have made the so-called metal–organic ... -
Metal-organic aerogels based on titanium(IV) for visible-light conducted CO2 photoreduction to alcohols
Angulo Ibáñez, Adrián; Perfecto Irigaray, Maite; Merino García, Iván; Luengo Ibarra, Naia; Goitandia, Amaia M.; Albo, Jonathan; Aranzabe Basterrechea, Estíbaliz; Beobide Pacheco, Garikoitz ; Castillo García, Oscar ; Pérez Yáñez, Sonia (Elsevier, 2022-12)Metal-organic frameworks (MOFs) imply an appealing source of photocatalysts as they combine porosity with tailorable electronic properties and surface chemistry. Herein, we report a series of unprecedented metal-organic ... -
Metal-organic porous materials for carbon dioxide valorization, water adsorption and photocatalitic hydrogen production
Perfecto Irigaray, Maite (2023-03-29)Esta tesis doctoral se fundamenta en el desarrollo de materiales metal-orgánicos porosos como son las redes metal-orgánicas (metal-organic frameworks, MOFs), los geles metal-orgánicos (metal-organic gels, MOGs) y los ... -
Métodos no convencionales para la preparación de polímeros de coordinación porosos. Una aproximación económica, medioambientalmente amigable y escalable
Lanchas González, Mónica (2015-07-16)En la última década, se ha puesto de relieve una nueva clase de material cristalino poroso con esqueleto híbrido, formado por la unión de iones o clústeres metálicos a través de ligandos puentes, los MOFs (Metal-Organic ...