Browsing Artículos-Grupo de investigación IMaCris / MaKrisI by Author "Bazan Blau, Begoña"
Now showing items 1-12 of 12
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Cationic Mn2+/H+ exchange leading a slow solid-state transformation of a 2D porphyrinic network at ambient conditions
Amayuelas López, Eder ; Fidalgo Marijuan, Arkaitz; Bazán Blau, Begoña del Pilar ; Urtiaga Greaves, Miren Karmele ; Barandika Argoitia, Miren Gotzone ; Lezama Diago, Luis María; Arriortua Marcaida, María Isabel (Elsevier, 2017-03)Metalloporphyrins exhibit outstanding chemical, physical and biological properties in dissolution, however, it is a challenge to synthesize them as stable solid frameworks. Long-time stability is crucial for future ... -
Coordination and crystallisation molecules: Their interactions affecting the dimensionality of metalloporphyrinic SCFs
Fidalgo Marijuan, Arkaitz; Amayuelas López, Eder ; Barandika Argoitia, Miren Gotzone ; Bazán Blau, Begoña del Pilar ; Urtiaga Greaves, Miren Karmele ; Arriortua Marcaida, María Isabel (MDPI, 2015-04-15)Synthetic metalloporphyrin complexes are often used as analogues of natural systems, and they can be used for the preparation of new Solid Coordination Frameworks (SCFs). In this work, a series of six metalloporphyrinic ... -
CuII-based metal-organic nanoballs for very rapid adsorption of dyes and iodine
Amayuelas López, Eder ; Fidalgo Marijuan, Arkaitz; Bazán Blau, Begoña del Pilar ; Urtiaga Greaves, Miren Karmele ; Barandika Argoitia, Miren Gotzone ; Arriortua Marcaida, María Isabel (The Royal Society of Chemistry, 2016-02-03)CuII nanoballs have been determined to be among the best MOPs (Metal–Organic Polyhedra) reported so far for the adsorption of small molecules, with the highlighting advantage of rapid kinetics, which focuses on their ... -
Encapsulation of β-alanine model amino-acid in zirconium(IV) metal organic frameworks: Defect engineering to improve host guest interactions
Rodríguez Muguruza, Asier; Fernández de Luis, Roberto; Iglesias, Naroa; Bazán Blau, Begoña del Pilar ; Urtiaga Greaves, Miren Karmele ; Serrano Larrea, Edurne; Fidalgo Marijuan, Arkaitz; Barandika Argoitia, Miren Gotzone (Elsevier, 2020-04)Metal-Organic Frameworks (MOFs) are porous coordination networks assembled through metal complexes with organic linkers. Due to their chemical versatility, these materials are being investigated for various applications ... -
Fe−TPP Coordination Network with Metalloporphyrinic Neutral Radicals and Face-to-Face and Edge-to-Face π−π Stacking
Fidalgo Marijuan, Arkaitz; Barandika Argoitia, Miren Gotzone ; Bazán Blau, Begoña del Pilar ; Urtiaga Greaves, Miren Karmele ; Lezama Diago, Luis María; Arriortua Marcaida, María Isabel (ACS Publications, 2013-06-25)Compound ([FeTPPbipy]•)n (TPP = meso-tetraphenylporphyrin and bipy = 4,4′-bipyridine) is the first example of a Fe−TPP−bipy coordination network, and it consists of 1D polymers packed through face-to-face and edge-to-face ... -
Heterogeneous catalytic properties of unprecedented m-O-[FeTCPP]2 dimers (H2TCPP = meso-tetra(4-carboxyphenyl)porphyrin): unusual superhyperfine EPR structure
Fidalgo Marijuan, Arkaitz; Barandika Argoitia, Miren Gotzone ; Bazán Blau, Begoña del Pilar ; Urtiaga Greaves, Miren Karmele ; Serrano Larrea, Edurne; Iglesias, Marta; Lezama Diago, Luis María; Arriortua Marcaida, María Isabel (RSC Publishing, 2015-01-07)During the past years, a great effort has been devoted to the anchoring of catalysts into solid coordination networks in order to achieve heterogeneous catalysts. In this sense, an innovative approach consists on using the ... -
Highly thermally stable heterogeneous catalysts: study of 0D and 3D porphyrinic MOFs
Amayuelas López, Eder ; Fidalgo Marijuan, Arkaitz; Bazán Blau, Begoña del Pilar ; Urtiaga Greaves, Miren Karmele ; Barandika Argoitia, Miren Gotzone ; Arriortua Marcaida, María Isabel (The Royal Society of Chemistry, 2017-11-13)Heterogeneous catalysts are a great bet for green chemistry in many industrial processes and, in the past decade, promising results have been achieved in order to improve the catalytic activity of Metal Organic Frameworks ... -
Mild Hydrothermal Synthesis, Crystal Structure, Thermal Behavior, Spectroscopic and Magnetic Properties of (NH4)0.80Li0.20[Fe(AsO4)F]
Berrocal Torres, Teresa; Mesa Rueda, José Luis; Serrano Larrea, Edurne; Bazán Blau, Begoña del Pilar ; Pizarro Sanz, José Luis ; Lezama Diago, Luis María; Rojo Aparicio, Teófilo ; Arriortua Marcaida, María Isabel (Elsevier, 2011-08-03)The (NH4)0.80Li0.20[Fe(AsO4)F] compound has been synthesized under mild hydrothermal conditions. The compound crystallize in the orthorhombic Pna21 space group, with cell parameters a= 13.352(9), b= 6.7049(9), c= 10.943(2) ... -
Mother structures related to the hexagonal and cubic close packing in Cu24 clusters: solvent-influenced derivatives
Amayuelas López, Eder ; Fidalgo Marijuan, Arkaitz; Barandika Argoitia, Miren Gotzone ; Bazán Blau, Begoña del Pilar ; Urtiaga Greaves, Miren Karmele ; Arriortua Marcaida, María Isabel (RSC Publishing, 2015-05-07)Compound 1 [Cu24(m BDC)24(DMF)20(H2O)4]• 24DMF•40H2O (m-BDC is 1,3-benzenedicarboxylate and DMF is N,N-dimethylformamide) has been synthesized and structurally characterized by X-ray diffraction. It consists of Cu24-clusters ... -
Self-assembly of iron TCPP (meso-tetra(4-carboxyphenyl)porphyrin) into a chiral 2D coordination polymer
Fidalgo Marijuan, Arkaitz; Barandika Argoitia, Miren Gotzone ; Bazán Blau, Begoña del Pilar ; Urtiaga Greaves, Miren Karmele ; Arriortua Marcaida, María Isabel (Elsevier, 2011-08-16)Synthetic metalloporphyrin complexes are often used as analogues of natural systems, and they can be used for the preparation of high-dimensional coordination polymers. In this work, a new chiral Fe-TCPP (TCPP is ... -
Thermal stability and crystallochemical analysis for CoII based coordination polymers with TPP and TPPS porphyrins
Fidalgo Marijuan, Arkaitz; Barandika Argoitia, Miren Gotzone ; Bazán Blau, Begoña del Pilar ; Urtiaga Greaves, Miren Karmele ; Arriortua Marcaida, María Isabel (RSC Publishing, 2013-03-16)Two new CoP–bipy compounds have been synthesised and characterised, where P is TPP for compound 1 (TPP = meso-tetraphenylporphyrin) and TPPS for compound 2 (TPPS = meso-tetraphenylporphinetetrasulfonic acid tetrasodium ... -
Water-induced phased transformation of a CuII-coordination framework with pyridine-2,5-dicarboxylate and di-2-pyridyl ketone: synchrotron radiation analysis
Fernández de Luis, Roberto; Bazán Blau, Begoña del Pilar ; Urtiaga Greaves, Miren Karmele ; Barandika Argoitia, Miren Gotzone ; Fidalgo Marijuan, Arkaitz; Llano Tomé, Francisco; Arriortua Marcaida, María Isabel (The Royal Society of Chemistry, 2015-07-09)Phase transformations in solid coordination frameworks (SCFs) are of interest for several applications, and this work reports on a crystal-to-crystal transformation found for a CuII-based SCF. Thus, combination of PDC and ...