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A Thiadiazole-capped Nanoribbon with 18 Linearly-Fused Rings

dc.contributor.authorCortizo Lacalle, Diego
dc.contributor.authorGozálvez Martínez, Cristian
dc.contributor.authorMelle Franco, Manuel
dc.contributor.authorMateo Alonso, Aurelio ORCID
dc.date.accessioned2019-06-27T11:11:19Z
dc.date.available2019-06-27T11:11:19Z
dc.date.issued2018-06-28
dc.identifier.citationNanoscale 10(24) : 11297-11301 (2018)es_ES
dc.identifier.issn2040-3364
dc.identifier.urihttp://hdl.handle.net/10810/34443
dc.description.abstractPolycyclic aromatic hydrocarbons that extend over 2 nm in one dimension are seen as monodisperse graphene nanoribbons, which have attracted significant attention for a broad range of applications in organic electronics and photonics. Herein we report the synthesis of a stable bisthiadiazole-capped pyrene-containing nanoribbon with 18 linearly fused rings (NR-18-TD). Thanks to the presence of alternating tert-butyl and tri-iso-butylsilyl groups, NR-18-TD is highly soluble in organic solvents and therefore its structure and fundamental optoelectronic, redox and electrical properties could be unambiguously established. This work illustrates that NR-18-TD is a promising soluble NR-based n-type semiconductor for applications in organic electronics.es_ES
dc.description.sponsorshipThe authors are grateful to the Basque Science Foundation for Science (Ikerbasque), POLYMAT, the University of the Basque Country (Grupo de Investigación GIU17/054 and SGIker), Gobierno de España (Ministerio de Economía y Competitividad CTQ2016-77970-R and CTQ2015-71936-REDT), Gobierno Vasco (BERC program), CICECO-Aveiro Institute of Materials, POCI-01-0145-FEDER-007679 (FCT ref. UID/CTM/50011/2013), Diputación Foral de Guipúzcoa (OF215/2016(ES)) and the FP7 framework program of the European Union (Marie Curie Career Integration Grant No. 618247 (NIRVANA)). This project has received funding from the European Union's Horizon 2020 research and innovation programme under grant agreement no. 664878. This project has also received funding from the European Research Council (ERC) under the European Union's Horizon 2020 research and innovation programme (grant agreement no. 722951)es_ES
dc.language.isoenges_ES
dc.publisherRoyal Society of Chemistryes_ES
dc.relationinfo:eu-repo/grantAgreement/EC/H2020/722951es_ES
dc.relationinfo:eu-repo/grantAgreement/EC/H2020/664878es_ES
dc.relationinfo:eu-repo/grantAgreement/EC/FP7/618247es_ES
dc.relationinfo:eu-repo/grantAgreement/MINECO/CTQ2016-77970-Res_ES
dc.relationinfo:eu-repo/grantAgreement/MINECO/CTQ2015-71936-REDTes_ES
dc.rightsinfo:eu-repo/semantics/openAccesses_ES
dc.subjectpolycyclic aromatic-hydrocarbonses_ES
dc.subjectthin-film transistorses_ES
dc.subjectn-heteroacenees_ES
dc.subjectgraphene nanoribbonses_ES
dc.subjectpyrazine-aceneses_ES
dc.subjectcove-edgees_ES
dc.subjectelectronicses_ES
dc.subjectacceptorses_ES
dc.subjectnonacenees_ES
dc.subjectribbonses_ES
dc.titleA Thiadiazole-capped Nanoribbon with 18 Linearly-Fused Ringses_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.rights.holder© The Royal Society of Chemistry 2018es_ES
dc.relation.publisherversionhttps://pubs.rsc.org/en/content/articlelanding/2018/nr/c8nr03516d#!divAbstractes_ES
dc.identifier.doi10.1039/c8nr03516d
dc.contributor.funderEuropean Commission
dc.departamentoesQuímica aplicadaes_ES
dc.departamentoeuKimika aplikatuaes_ES


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