| dc.contributor.author | Santos Ruiz, Jesús Manuel de los | |
| dc.contributor.author | Ochoa Díez, Zelai | |
| dc.contributor.author | Palacios Gambra, Francisco Javier  | |
| dc.date.accessioned | 2013-07-12T10:19:25Z | |
| dc.date.available | 2013-07-12T10:19:25Z | |
| dc.date.issued | 2012 | |
| dc.identifier.citation | ARKIVOC 4: 54-62 (2012) | es |
| dc.identifier.issn | 1551-7012 | |
| dc.identifier.uri | http://hdl.handle.net/10810/10413 | |
| dc.description | Issue in Honor of Prof. Paweł Kafarski | en |
| dc.description.abstract | [EN] The reactivity of new three carbon synthon, generated in situ from the reaction of electrondeficient allenes with an appropriate phosphine as the catalyst, toward pronucleophilic reagents is described. Triphenylphosphine-catalyzed reaction of allenes derived from phosphine oxides with nitrogen- or carbonucleophiles gave the γ-addition product as a mixture of cis and trans isomers. | en |
| dc.language.iso | eng | en |
| dc.publisher | ARKAT USA, Inc | en |
| dc.rights | info:eu-repo/semantics/openAccess | en |
| dc.subject | allenyl phosphine oxide | en |
| dc.subject | phosphine catalysis | en |
| dc.subject | pronucleophiles | en |
| dc.subject | umpolung addition | en |
| dc.subject | α,β-unsaturated phosphine oxides | en |
| dc.title | Stereoselective inverse conjugate addition of nitrogen and carbon nucleophiles to allenyl phosphine oxide. Synthesis of α,β-unsaturated phosphine oxides | en |
| dc.type | info:eu-repo/semantics/article | en |
| dc.rights.holder | © ARKAT-USA, Inc. This work is licensed under a Creative Commons Attribution-NonCommercial 3.0 License. | en |
| dc.relation.publisherversion | http://quod.lib.umich.edu/cgi/p/pod/dod-idx/stereoselective-inverse-conjugate-addition-of-nitrogen.pdf?c=ark;idno=5550190.0013.406 | en |
| dc.departamentoes | Química orgánica I | es_ES |
| dc.departamentoeu | Kimika organikoa I | es_ES |
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