| dc.contributor.author | Gómez San Juan, Asier | |
| dc.contributor.author | Sotomayor Anduiza, María Nuria | |
| dc.contributor.author | Lete Expósito, María Esther | |
| dc.date.accessioned | 2014-02-03T15:20:52Z | |
| dc.date.available | 2014-02-03T15:20:52Z | |
| dc.date.issued | 2013-02 | |
| dc.identifier.citation | Beilstein Journal of Organic Chemistry 9 : 313-322 (2013) | es |
| dc.identifier.issn | 1860-5397 | |
| dc.identifier.uri | http://hdl.handle.net/10810/11329 | |
| dc.description.abstract | In this review we summarize recent developments in inter- and intramolecular enantioselective carbolithiation reactions carried out in the presence of a chiral ligand for lithium, such as (-)-sparteine, to promote facial selection on a C=C bond. This is an attractive approach for the construction of new carbon-carbon bonds in an asymmetric fashion, with the possibility of introducing further functionalization on the molecule by trapping the reactive organolithium intermediates with electrophiles. | es |
| dc.description.sponsorship | Ministerio de Ciencia e Innovacion (CTQ2009-07733) and Universidad del Pais Vasco/Euskal Herriko Unibertsitatea (UFI11/22, GIU 0946) for their financial support. Technical and personnel support provided by Servicios Generales de Investigacion SGIker (UPV/EHU, MICINN, GV/EJ, ERDF and ESF) is gratefully acknowledged. We also thank UPV/EHU for a postdoctoral grant (A.G). | es |
| dc.language.iso | eng | es |
| dc.publisher | Beilstein Institut | es |
| dc.relation | info:eu-repo/grantAgreement/MICINN/CTQ2009-07733 | |
| dc.rights | info:eu-repo/semantics/openAccess | es |
| dc.subject | alkenes | es |
| dc.subject | asymmetric synthesis | es |
| dc.subject | carbolithiation | es |
| dc.subject | carbometallation | es |
| dc.subject | enantioselectivity | es |
| dc.subject | lithium | es |
| dc.title | Inter- and intramolecular enantioselective carbolithiation reactions | es |
| dc.type | info:eu-repo/semantics/article | es |
| dc.rights.holder | © 2013 Gómez-SanJuan et al; licensee Beilstein-Institut. This is an Open Access article under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (http://www.beilstein-journals.org/bjoc) | es |
| dc.relation.publisherversion | http://www.beilstein-journals.org/bjoc/single/articleFullText.htm?publicId=1860-5397-9-36 | es |
| dc.identifier.doi | 10.3762/bjoc.9.36 | |
| dc.departamentoes | Química orgánica II | es_ES |
| dc.departamentoeu | Kimika organikoa II | es_ES |
| dc.subject.categoria | CHEMISTRY, ORGANIC | |
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