BackExaminar Artículos, Comunicaciones, Libros por departamento (cas.) "Química Orgánica e Inorgánica"
Now showing items 1-20 of 118
-
1D Zn(ii)/2D Cu(i) halogen pyridyl coordination polymers. Band gap engineering by DFT for predicting more efficient photocatalysts in water treatment
; ; Castillo García, Oscar
; (RSC, 2024-11)
One of the key factors determining the photocatalytic capacity of a compound is its optical band gap, which, within an optimal range, maximizes the absorption and utilization of solar light. Recent research shows that ... -
A Lamellar Zn-Based Coordination Polymer Showing Increasing Photoluminescence upon Dehydration
; ; Castillo García, Oscar; Luque Arrebola, Antonio ; ; ; (MDPI, 2023-07-25)
The present study reports on a 2D lamellar coordination polymer (CP) of {[Zn(µ3-pmdc)(H2O)]·H2O}n formula (pmdc = pyrimidine-4,6-dicarboxylate). This CP is synthesized under an appropriate acid-base reaction between the ... -
A metal-organic framework based on Co(II) and 3-aminoisonicotinate showing specific and reversible colourimetric response to solvent exchange with variable magnet behaviour
; Pérez Yáñez, Sonia; ; Beobide Pacheco, Garikoitz ; ; ; Seco Botana, José Manuel ; (Elsevier, 2022-06)
[EN] A versatile metal-organic system consisting of Co-based compounds that show reversible transformations between a 3D metal-organic framework (MOF) of {[Co(mu-3isoani)(2)]center dot DMF}(n) (1) formula (where 3isoani - ... -
A Milestone in the Chemical Synthesis of Fe3O4 Nanoparticles: Unreported Bulklike Properties Lead to a Remarkable Magnetic Hyperthermia
; ; ; ; ; ; ; Orue Goikuria, Iñaki; ; (ACS, 2021-11-10)
Among iron oxide phases, magnetite (Fe3O4) is often the preferred one for nanotechnological and biomedical applications because of its high saturation magnetization and low toxicity. Although there are several synthetic ... -
A synergistic exploitation to produce high-voltage quasi-solid-state lithium metal batteries
Wu, Junru; Wang, Xianshu; Liu, Qi; Wang, Shuwei; Zhou, Dong; Kang, Feiyu; Shanmukaraj, Devaraj; Armand, Michel; Rojo Aparicio, Teófilo; Li, Baohua; Wang, Guoxiu (Nature Research, 2021-09-30)
[EN]The energy content increase is of paramount importance for the development of future Li-based batteries. Here, the authors propose a gel polymer electrolyte in combination with a positive electrode comprising of a ... -
Absence of Intermediates in the BINOL-Derived Mg(II)/Phosphate-Catalyzed Desymmetrizative Ring Expansion of 1-Vinylcyclobutanols
; ; Uria Pujana, Uxue; ; ; Vicario Hernando, José Luis ; (American Chemical Society, 2021-12)
[EN] The catalyzed desymmetrizative ring expansion of alkenylcyclobutanols promoted by halofunctionalization of the alkene moiety with Nbromosuccinimide has been experimentally and computationally studied. The reaction ... -
Amide-Directed Intramolecular Co(III)-Catalyzed C-H Hydroarylation of Alkenes for the Synthesis of Dihydrobenzofurans with a Quaternary Center
(American Chemical Society, 2020-07-17)The first example of Cp*Co(III)-catalyzed intramolecular hydroarylation of allyl aryl ethers using an amide directing group for the preparation of 3,3-disubstituted dihydrobenzofurans in high yields is described. The ... -
Amorphous FeCoCrSiB Ribbons with Tailored Anisotropy for the Development of Magnetic Elements for High Frequency Applications
Kurlyandskaya, Galina; ; Pasynkova, Anna ; Volchkov, Stanislav ; Lukshina, Wera ; Larrañaga Varga, Aitor ; Dmitrieva (Bryantseva), Natalia ; ; Orue Goikuria, Iñaki (MDPI, 2022)
The ferromagnetic resonance (FMR) in the frequency range of 0.5 to 12.5 GHz has been investigated as a function of external magnetic field for rapidly quenched Fe3Co67Cr3Si15B12 amorphous ribbons with different features ... -
An Approach to the Synthesis of a Hepatitis C Virus Inhibitor through a Proline-Catalyzed 1,3-Dipolar Cycloaddition Using Acrolein
; ; Prieto Aretxabaleta, Liher; Uria Pujana, Uxue ; Carrillo Fernández, María Luisa ; Vicario Hernando, José Luis (Thieme, 2021-09-06)
An efficient and easy protocol for performing 1,3-dipolar cycloaddition using azomethine ylides and acrolein is presented. The reaction catalyzed by d-proline allows the synthesis of C-3 unsubstituted pyrrolidines. The ... -
An easy and simple method for the immobilization of dyes through click reactions: activated alkyne, copper not needed
; ; ; Vilas Vilela, José Luis; (RSC, 2024)
The copper-free azide–alkyne click reaction has shown to be a successful alternative to immobilize covalently a fluorescente compound onto poly(-L-lactic) acid (PLLA) surfaces. Proceded by basic hydrolysis and amidation ... -
Antimicrobials in Eisenia fetida earthworms: A comprehensive study from method development to the assessment of uptake and degradation
; ; ; ; ; Soto López, Manuel; ; (Elservier, 2024-04-20)
In this work, an accurate analytical method was developed for the simultaneous analysis of twenty-seven antimicrobials (AMs) in earthworms using liquid chromatography coupled to a triple quadrupole mass spectrometry detector ... -
Asymmetric Dual Enamine Catalysis/Hydrogen Bonding Activation
; Prieto Aretxabaleta, Liher; Uria Pujana, Uxue ; Carrillo Fernández, María Luisa ; Vicario Hernando, José Luis (MDPI, 2023-07-11)
Asymmetric enamine base activation of carbonyl compounds is a well-known and widely used strategy for providing functionalization of organic compounds in an efficient way. The use of solely organic substances, which in ... -
Asymmetric Organocatalysis: A Survival Guide to Medicinal Chemists
; Prieto Aretxabaleta, Liher; (MDPI, 2022-12-29)
Majority of drugs act by interacting with chiral counterparts, e.g., proteins, and we are, unfortunately, well-aware of how chirality can negatively impact the outcome of a therapeutic regime. The number of chiral, non-racemic ... -
Asymmetric Synthesis of Adjacent Tri- and Tetrasubstituted Carbon Stereocenters: Organocatalytic Aldol Reaction of an Hydantoin Surrogate with Azaarene 2-Carbaldehydes
; ; ; ; Mercero Larraza, José María; ; Oyarbide Garmendia, Juan Miguel ; (Wiley-VCH, 2019-07-18)
A bifunctional amine/squaramide catalyst promoted direct aldol addition of an hydantoin surrogate to pyridine 2-carbaldehyde N-oxides to afford adducts bearing two vicinal tertiary/quaternary carbons in high diastereo- and ... -
Atomic and Specificity Details of Mucin 1 O-Glycosylation Process by Multiple Polypeptide GalNAc-Transferase Isoforms Unveiled by NMR and Molecular Modeling
Coelho, Helena; De las Rivas, Matilde; Grosso, Ana S.; Diniz, Ana; Soares, Cátia O.; Francisco, Rodrigo A.; Dias, Jorge S.; Compañón, Ismael; Sun, Lingbo; Narimatsu, Yoshiki; Vakhrushev, Sergey Y.; Clausen, Henrik; Cabrita, Eurico J.; Jiménez Barbero, Jesús; Corzana, Francisco; Hurtado Guerrero, Ramón; Marcelo, Filipa (American Chemical Society, 2022-02-24)
[EN] The large family of polypeptide GalNAc-transferases (GalNAc-Ts) controls with precision how GalNAc O-glycans are added in the tandem repeat regions of mucins (e.g., MUC1). However, the structural features behind the ... -
Biomimetic Tweezers for N-Glycans: Selective Recognition of the Core GlcNAc(2) Disaccharide of the Sialylglycopeptide SGP
; ; ; ; Jiménez Barbero, Jesús; ; (Wiley, 2023-03)
In recent years, glycomics have shown how pervasive the role of carbohydrates in biological systems is and how chemical tools are essential to investigate glycan function and modulate carbohydrate-mediated processes. ... -
Brønsted Acid Catalyzed (4 + 2) Cyclocondensation of 3-Substituted Indoles with Donor–Acceptor Cyclopropanes
; Uria Pujana, Uxue; ; Prieto Aretxabaleta, Liher ; ; ; Vicario Hernando, José Luis (ACS Publications, 2021-03)
Acylcyclopropanes are employed as useful donor−acceptor cyclopropanes that undergo formal (4 + 2) cyclo-condensation with N-unprotected 3-substituted indoles in thepresence of a Brønsted acid catalyst. The reaction involves ... -
Catalyst-Free Amino-Yne Click Reaction: An Efficient Way for Immobilizing Amoxicillin onto Polymeric Surfaces
; ; ; ; Vilas Vilela, José Luis; (MDPI, 2024-01-15)
Surface modifications play a crucial role in enhancing the functionality of biomaterials. Different approaches can be followed in order to achieve the bioconjugation of drugs and biological compounds onto polymer surfaces. ... -
Combined experimental and theoretical investigation on the magnetic properties derived from the coordination of 6-methyl-2- oxonicotinate to 3d-metal ions
; ; ; ; ; ; San Sebastián Larzabal, Eider; (Royal Society of Chemistry, 2022-06-08)
Five new compounds are reported herein starting from 2-hydroxy-6-methylnicotinic acid (H2h6mnic) and first-row transition metal ions, although H2h6mnic shows a prototropy in solution to lead to the 6-methyl-2-oxonicotinate ... -
Consecutive Single-Crystal-to-Single-Crystal Isomerization of Novel Octamolybdate Anions within a Microporous Hybrid Framework with Robust Water Sorption Properties
; ; ; ; Beobide Pacheco, Garikoitz; San Felices Mateos, Leire ; ; Gutiérrez Zorrilla López, Juan Manuel ; ; (Wiley, 2023-10)
The 3D hybrid framework [{Cu(cyclam)}3(κ-Mo8O27)] ⋅ 14H2O (1) (cyclam=1,4,8,11-tetraazacyclotetradecane) undergoes sequential single-crystal-to-single-crystal transformations upon heating to afford two different anhydrous ...