BackExaminar Artículos, Comunicaciones, Libros por departamento (cas.) "Química aplicada"
Now showing items 1-20 of 253
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2D-Coordination polymers based on 1H-indazole-4-carboxylic acid and transition metal ions: magnetic, luminescence and biological properties
(Royal Society of Chemistry, 2020-08-14)We report the formation of five novel multifunctional coordination polymers based on 1H-indazole-4-carboxylic acid (HL). To the best of our knowledge, these complexes are the first examples of coordination compounds ... -
A 3D bioelectrical interface to assess colorectal cancer progression in vitro
(Elsevier, 2022-06)Conducting polymers such as PEDOT have attracted considerable attention in the tissue engineering field to add an active electrical read-out to 3D cell cultures. However, PEDOT is normally copolymerized with PSS− that ... -
A family of Cd(ii) coordination polymers constructed from 6-aminopicolinate and bipyridyl co-linkers: study of their growth in paper and photoluminescence sensing of Fe3+ and Zn2+ ions
; ; ; ; ; ; Seco Botana, José Manuel
; (RSC, 2024-06)
In this work, we report on five novel coordination polymers (CPs) based on the linkage of the [Cd(6apic)2] building block [where 6apic = 6-aminopicolinate] by different bipyridine-type organic spacers, forming different ... -
A First Evaluation of the Usefulness of Kudzu Starch in Cultural Heritage Restoration
Lama Ochoa de Retana, Estibaliz; ; Prieto Taboada, Nagore ; ; Rodríguez Laso, María Dolores ; Madariaga Mota, Juan Manuel (Nature, 2020-09-24)
In recent times, the use of natural and harmless products for the environment and restorer is taking place in the field of Cultural Heritage restoration. In this sense, wheat, rice and corn starches as adhesives, have ... -
A Green Synthesis of Nanocatalysts Based on Reduced Graphene Oxide/Magnetic Nanoparticles for the Degradation of Acid Red 1
; ; González de San Román, Estibaliz; Sanz Iturralde, Oihane ; ; ; (The Royal Society of Chemistry, 2020-10-26)
The increasing amount of organic dye-polluted wastewater from the textile industry makes the development of techniques for the efficient purification and reuse of wastewater an urgent issue. Accordingly, solid adsorbents ... -
A Lamellar Zn-Based Coordination Polymer Showing Increasing Photoluminescence upon Dehydration
; ; Castillo García, Oscar; Luque Arrebola, Antonio ; ; ; (MDPI, 2023-07-25)
The present study reports on a 2D lamellar coordination polymer (CP) of {[Zn(µ3-pmdc)(H2O)]·H2O}n formula (pmdc = pyrimidine-4,6-dicarboxylate). This CP is synthesized under an appropriate acid-base reaction between the ... -
A Luminescent MOF Based on Pyrimidine-4,6-dicarboxylate Ligand and Lead(II) with Unprecedented Topology
(MDPI, 2023-10-13)In the present work, we report on a 3D MOF of {[Pb5(μ3-OH)(μ3-NO3)3(μ6-pmdc)3]·H2O}n formula (pmdc = pyrimidine-4,6-dicarboxylate) synthesized by an oven-heated, solvent-free procedure. The large connectivity afforded by ... -
A metal-organic framework based on Co(II) and 3-aminoisonicotinate showing specific and reversible colourimetric response to solvent exchange with variable magnet behaviour
; Pérez Yáñez, Sonia; ; Beobide Pacheco, Garikoitz ; ; ; Seco Botana, José Manuel ; (Elsevier, 2022-06)
[EN] A versatile metal-organic system consisting of Co-based compounds that show reversible transformations between a 3D metal-organic framework (MOF) of {[Co(mu-3isoani)(2)]center dot DMF}(n) (1) formula (where 3isoani - ... -
A methodology for the selection and characterization of riboflavin-overproducing Weissella cibaria strains after treatment with roseoflavin
; ; ; ; ; ; Dueñas Chasco, María Teresa; (Frontiers Media, 2023-04)
Fermentative processes by lactic acid bacteria can produce metabolites of interest to the health and food industries. Two examples are the production of B-group vitamins, and of prebiotic and immunomodulatory dextran-type ... -
A Mixed Heterobimetallic Y/Eu-MOF for the Cyanosilylation and Hydroboration of Carbonyls
; ; ; ; ; Seco Botana, José Manuel; ; (MDPI, 2022-03-06)
Herein, to the best of our knowledge, the first heterobimetallic Y/Eu porous metal–organic framework (MOF), based on 3-amino-4-hydroxybenzoic acid (H2L) ligand, with the following formulae {[Y3.5Eu1.5L6(OH)3(H2O)3]·12DMF}n ... -
A novel Candida albicans Als3, Hwp1 and Met6 derived complex peptide protects mice against hematogenously induced candidiasis
; Arrieta Aguirre, Inés; Carrano, Giulia ; ; Moragues Tosantos, María Dolores (Elsevier, 2024-08)
Candida albicans can cause superficial or systemic infections in humans, particularly in immunocompromised individuals. Vaccination strategies targeting specific antigens of C. albicans have shown promise in providing ... -
A Potassium Metal-Organic Framework based on Perylene- 3,4,9,10-tetracarboxylate as Sensing Layer for Humidity Actuators
Seco Botana, José Manuel; San Sebastián Larzabal, Eider ; ; ; ; ; ; ; Gómez-Ruiz, Santiago ; ; ; (Nature Publishing, 2018-09-26)
We have synthesized a novel three-dimensional metal-organic-framework (MOF) based on the perylene-3,4,9,10-tetracarboxylate linker and potassium as metallic centre. We report the formation of this K-based MOF using ... -
A Sterically Congested Nitrogenated Benzodipentaphene with a Double π-Expanded Helicene Structure
Chen, Fengkun; ; ; ; Mateo Alonso, Aurelio (American Chemical Society, 2020-05-01)
Herein, we describe a series of three sterically congested nitrogenated benzodipentaphenes, one of which shows a highly distorted aromatic backbone with an unprecedented double π-expanded helicene structure. -
A Thiadiazole-capped Nanoribbon with 18 Linearly-Fused Rings
Cortizo Lacalle, Diego; Gozálvez Martínez, Cristian; Melle Franco, Manuel; Mateo Alonso, Aurelio (Royal Society of Chemistry, 2018-06-28)
Polycyclic aromatic hydrocarbons that extend over 2 nm in one dimension are seen as monodisperse graphene nanoribbons, which have attracted significant attention for a broad range of applications in organic electronics and ... -
A Versatile Chemoenzymatic Nanoreactor that Mimics NAD(P)H Oxidase for the In Situ Regeneration of Cofactors
(Wiley, 2022-09)Herein, we report a multifunctional chemoenzymatic nanoreactor (NanoNOx) for the glucose-controlled regeneration of natural and artificial nicotinamide cofactors. NanoNOx are built of glucose oxidase-polymer hybrids that ... -
Accelerated ageing of hybrid acrylic waterborne coatings containing metal oxide nanoparticles: effect on the microstructure
Aguirre Arrese, Miren; ; ; ; Leiza Recondo, José Ramón (Elsevier, 2017-05-05)
This work analyses the effect of UV radiation in a pure acrylic film, and two hybrid films, one with 1% CeO2 nanoparticles and another with 1% of ZnO nanoparticles. The long term durability of the polymeric films was studied ... -
Acidic Aqueous-Phase Copolymerization of AA and HPEG Macromonomer: Influence of Monomer Concentration on Reactivity Ratios
; ; ; ; Leiza Recondo, José Ramón (ACS, 2023-10-30)
Poly(acrylic acid-co-polyethylene glycol 2-methyl-2-propenyl ether) copolymers are comb-like water-soluble copolymers produced by the copolymerization of acrylic acid (AA) and polyethylene glycol 2-methyl-2-propenyl ether ... -
Adaptation of the Folin-Ciocalteu and Fast Blue BB spectrophotometric methods to digital image analysis for the determination of total phenolic content: Reduction of reaction time, interferences and sample analysis
; Bordagaray Eizaguirre, Ane; ; ; Ostra Beldarrain, Miren ; (Elsevier, 2024-02)
The Folin-Ciocalteu (FC) method is the most common method used for total phenolic content (TPC) determination, but in recent years, a more specific method that does not detect non-phenolic reducing compounds has been ... -
Adsorptive Capacity, Inhibitory Activity and Processing Techniques for a Copper-MOF Based on the 3,4-Dihydroxybenzoate Ligand
; ; ; ; ; ; ; ; ; ; ; Seco Botana, José Manuel (MDPI, 2022-11-21)
Due to the fast, emerging development of antibiotic-resistant bacteria, the need for novel, efficient routes to battle these pathogens is crucial; in this scenario, metal-organic frameworks (MOFs) are promising materials ... -
Advances and Applications of Block Copolymers
(MDPI, 2023-07-02)Polymers are materials that have constantly evolved from the beginning of their discovery until the present day. During the last few decades, polymers have been used in many areas of science and cutting-edge research and ...