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Overcoming the Limitations of Organocatalyzed Glycolysis of Poly(ethylene terephthalate) to Facilitate the Recycling of Complex Waste Under Mild Conditions
(ACS, 2024-03)
Although multiple methods have been reported in the literature for the chemical recycling of poly(ethylene terephthalate) (PET), large-scale depolymerization is not yet widely employed. The main reasons for the limited ...
Degradable Alternating Copolymers by Radical Copolymerization of 2-Methylen-1,3-dioxepane and Crotonate Esters
(ACS, 2024-03)
Producing backbone degradable copolymers via free-radical copolymerization is a promising, yet challenging method to develop more sustainable materials for many applications. In this work, we present the copolymerization ...
Boosting the Reactivity of Bis-Lactones to Enable Step-Growth Polymerization at Room Temperature
(ACS, 2024-03)
The development of new sustainable polymeric materials endowed with improved performances but minimal environmental impact is a major concern, with polyesters as primary targets. Lactones are key monomers thanks to ...
The ABC of Generalized Coordination Numbers and Their Use as a Descriptor in Electrocatalysis
(Wiley, 2023-07)
The quest for enhanced electrocatalysts can be boosted by descriptor-based analyses. Because adsorption energies are the most common descriptors, electrocatalyst design is largely based on brute-force routines that comb ...
Multicoverage Study of Femtosecond Laser-Induced Desorption of CO from Pd(111)
(ACS, 2024-02)
We study the strong coverage dependence of the femtosecond laser-induced desorption of CO from Pd(111) using molecular dynamics simulations that consistently include the effect of the laser-induced hot electrons on both ...
One- and Two-Electron Reductions in MiniSOG and their Implication in Catalysis
(Wiley, 2023-08)
The unconventional bioorthogonal catalytic activation of anticancer metal complexes by flavin and flavoproteins photocatalysis has been reported recently. The reactivity is based on a two-electron redox reaction of the ...
Comparison of the Magnetic and Structural Properties of MnFePSi Microwires and MnFePSi Bulk Alloy
(MDPI, 2024-04-18)
We provide comparative studies of the structural, morphological, microstructural, and magnetic properties of MnFePSi-glass-coated microwires (MnFePSi-GCMWs) and bulk MnFePSi at different temperatures and magnetic fields. ...
Dependence of Magnetic Properties of As-Prepared Nanocrystalline Ni2MnGa Glass-Coated Microwires on the Geometrical Aspect Ratio
(MDPI, 2024-06-06)
We have prepared NiMnGa glass-coated microwires with different geometrical aspect ratios, ρ = dmetal/Dtotal (dmetal—diameter of metallic nucleus, and Dtotal—total diameter). The structure and magnetic properties are ...
Controlling of the single domain wall propagation in magnetic microwires by magnetostatic interaction
(Elsevier, 2024-06)
Ultrafast magnetization switching through the single domain wall (DW) propagation has been reported in amorphous micrometric and submicrometric wires. However the performance of prospective devices utilizing DW propagation ...
Crystallization-induced self-assembly of poly(ethylene glycol) side chains in dithiol–yne-based comb polymers: side chain spacing and molecular weight effects
(ACS, 2024-05)
The chain architecture and topology of macromolecules impact their physical properties and final performance, including their crystallization process. In this work, comb polymers constituted by poly(ethylene glycol), PEG, ...