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Exploring the Slow Magnetic Relaxation of a Family of Photoluminescent 3D Lanthanide–Organic Frameworks Based on Dicarboxylate Ligands
(MDPI, 2021-03-16)
A family of metal–organic frameworks with general formula {[Nd2(ant)2((NH2)2-bdc)(DMF)4]·2DMF}n (1) and {[Ln2(ant)2((NH2)2-bdc)(DMF)4]·2DMF·2H2O}n (Ln = Tb (2), Ho (3), and Er (4)) has been obtained from reactions between ...
Single-Molecule Magnets: From Mn12-ac to dysprosium metallocenes, a travel in time
(Elsevier, 2021-05-07)
The discovery of the first Single-Molecule Magnet, Mn12-ac, in 1993 changed the perspective of how information
can be stored. The current bit, occupying few hundreds of nanometers in present devices, would be
minimized ...
Synthesis, Structural Features and Physical Properties of a Family of Triply Bridged Dinuclear 3d-4f Complexes
(MDPI, 2021-02-05)
New dinuclear MII-LnIII complexes of general formulas [Cu(µ-L)(µ-OAc)Ln(NO3)2]·CH3CN·H2O (LnIII = Gd (1), Tb (2), Dy (3) and Er (4)), [Ni(CH3CN)(µ-L)(µ-OAc)Ln(NO3)2]·CH3CN (LnIII = Nd (5), Gd (6), Tb (7), Dy (8), Er (9) ...