Browsing Artículos by Author "Chaplin, Adrian B."
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Iridium complexes of an ortho-trifluoromethylphenyl substituted PONOP pincer ligand
Poole, Ethan W.; Bustos Rosas, Itxaso; Hood, Thomas M.; Smart, Jennifer E.; Chaplin, Adrian B. (Royal Society of Chemistry, 2023)The synthesis and iridium coordination chemistry of a new pyridine-based phosphinito pincer ligand 2,6- (ArF2PO)2 C5H 3N (PONOP-ArF ; ArF = 2-(CF3)C 6 H4 ) are described, where the P-donors have ortho- trifluoromethylphenyl ... -
Stability and C–H Bond Activation Reactions of Palladium(I) and Platinum(I) Metalloradicals: Carbon-to-Metal H-Atom Transfer and an Organometallic Radical Rebound Mechanism
Krämer, Tobias; Bustos Rosas, Itxaso; Sinclair, Matthew J. G.; Gyton, Matthew R.; Tan, Sze-yin; Wedge, Christopher J.; Macgregor, Stuart A.; Chaplin, Adrian B. (ACS, 2023-06-15)One-electron oxidation of palladium(0) and platinum(0) bis(phosphine) complexes enables isolation of a homologous series of linear d9 metalloradicals of the form [M(PR3)2]+ (M = Pd, Pt; R = tBu, Ad), which are stable in ...