Browsing Artículos by Author "Martín Matute, Belén"

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      An Expedient Method for the Umpolung Coupling of Enols with Heteronucleophiles 

      García Vázquez, Víctor; Carretero Cerdán, Alba ORCID; Sanz-Marco, Amparo ORCID; Gómez Bengoa, Enrique; Martín Matute, Belén (Wiley, 2022-08)
      [EN] In this paper, we present an unprecedented and general umpolung protocol that allows the functionalization of silyl enol ethers and of 1,3-dicarbonyl compounds with a large range of heteroatom nucleophiles, including ...
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      An umpolung strategy to react catalytic enols with nucleophiles 

      Sanz Marco, Amparo; Martínez Erro, Samuel; Pauze, Martin Paule; Gómez Bengoa, Enrique; Martín Matute, Belén (Nature, 2019-11-20)
      The selective synthesis of a-functionalized ketones with two similar enolizable positions can be accomplished using allylic alcohols and iridium(III) catalysts. A formal 1,3-hydrogen shift on allylic alcohols generates ...