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Tailoring the physical properties of hybrid magnetic quinuclidine-based plastic compounds via weak interactions
(Royal Society of Chemistry, 2023)
Herein we explore the opportunities arising from combining bicyclic amine cations with halometallate anions to build organic–inorganic hybrid materials. We will use the crystal engineering approach in these materials, ...
From Lab to Manufacturing Line: Guidelines for the Development and Upscaling of Aqueous Processed NMC622 Electrodes
(The Electrochemical Society, 2023-01-24)
Lithium-ion batteries (LIBs) have facilitated the transition to a more sustainable energy model. Paradoxically, current high energy cathodes are industrially processed using organic solvents, which are deleterious for the ...
Copper(II) invigorated EHU-30 for continuous electroreduction of CO2 into value-added chemicals
(Nature, 2022-05-20)
The doping of zirconium based EHU-30 and EHU-30-NH2 metal-organic frameworks with copper(II) yielded a homogeneous distribution of the dopant with a copper/zirconium ratio of 0.04-0.05. The doping mechanism is analysed by ...
Asymmetric Organocatalysis: A Survival Guide to Medicinal Chemists
(MDPI, 2022-12-29)
Majority of drugs act by interacting with chiral counterparts, e.g., proteins, and we are, unfortunately, well-aware of how chirality can negatively impact the outcome of a therapeutic regime. The number of chiral, non-racemic ...
Metal-organic aerogels based on titanium(IV) for visible-light conducted CO2 photoreduction to alcohols
(Elsevier, 2022-12)
Metal-organic frameworks (MOFs) imply an appealing source of photocatalysts as they combine porosity with tailorable electronic properties and surface chemistry. Herein, we report a series of unprecedented metal-organic ...
Synthetic Zwitterionic Streptococcus pneumoniae Type 1 Oligosaccharides Carrying Labile O-Acetyl Esters
(Wiley, 2023-01)
We herein report the first total synthesis of the Streptococcus pneumoniae serotype 1 (Sp1) oligosaccharide, a unique zwitterionic capsular polysaccharide carrying labile O-acetyl esters. The target oligosaccharides, ...
Metal-Catalyzed Cascade Reactions between Alkynoic Acids and Dinucleophiles: A Review
(MDPI, 2023-02-28)
Cascade reactions provide a straightforward access to many valuable compounds and reduce considerably the number of steps of a synthetic sequence. Among the domino and multicomponent processes that involve alkynes, the ...
Thiosemicarbazonecopper/Halido Systems: Structure and DFT Analysis of the Magnetic Coupling
(MDPI, 2023-01-03)
Experimental magnetic studies performed on the [{CuLX}2] system (HL = pyridine-2-carbaldehyde thiosemicarbazone, X = Cl−, Br−, I−) point to the larger electronegativity in X, the lower magnitude of the antiferromagnetic ...
The Effects of Mono- and Bivalent Linear Alkyl Interlayer Spacers on the Photobehavior of Mn(II)-Based Perovskites
(MDPI, 2023-02-07)
Mn(II)-based perovskite materials are being intensively explored for lighting applications; understanding the role of ligands regarding their photobehavior is fundamental for their development. Herein, we report on two Mn ...
Fast Visible-Light Photopolymerization in the Presence of Multiwalled Carbon Nanotubes: Toward 3D Printing Conducting Nanocomposites
(American Chemical Society, 2022-02)
[EN] A new photoinitiator system (PIS) based on riboflavin (Rf), triethanolamine, and multiwalled carbon nanobutes (MWCNTs) is presented for visible-light-induced photopolymerization of acrylic monomers. Using this PIS, ...