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A Robust Framework Based on Polymeric Octamolybdate Anions and Copper(II) Complexes of Tetradentate N-donor Ligands
(MDPI, 2018-01-06)
A new organic-inorganic compound based on octamolybdate building blocks and copper(II) complexes of tetradentate N-donor ligands has been hydrothermally synthesized, namely [Cu(cyclam)](2)[Mo8O26]center dot 1.5H(2)O (1), ...
Synthesis and structural characterisation of [Cu2[(PDC)2(bpa)(H2O)2]•nH2O•mDMF (n=3 and m=1 for 1, n=7 and m=0 for 2, PDC=2,5-pyrindinedicarboxylate and bpa= 1,2-di(4-pyridil)ethane))
(2016-02-16)
[EN] Combination of polycarboxylate anions and dipyridyl ligands is an effective strategy to produce solid coordination frameworks (SCF) which are crystalline materials based on connections between metal ions through organic ...
Aerogels of 1D Coordination Polymers: From a Non-Porous Metal-Organic Crystal Structure to a Highly Porous Material
(MDPI, 2016-01-15)
The processing of an originally non- porous 1D coordination polymer as monolithic gel, xerogel and aerogel is reported as an alternative method to obtain novel metal- organic porous materials, conceptually different to ...
Slot-Die Process of a Sol–Gel Photocatalytic Porous Coating for Large-Area Fabrication of Functional Architectural Glass
(MDPI, 2021-06-06)
The slot-die process is an appealing technology for the fabrication of coatings on large-area substrates. However, its application on the production of photocatalytic coatings based on sol–gel formulations remains virtually ...
Magnetic and Photoluminescent Sensors Based on Metal-Organic Frameworks Built up from 2-aminoisonicotinate
(2020-06-01)
In this work, three isostructural metal-organic frameworks based on first row transition metal ions and 2-aminoisonicotinate (2ain) ligands, namely, {[M(mu-2ain)2]·DMF}n [MII=Co (1), Ni (2), Zn (3)], are evaluated for their ...
On the Road to Sustainable Energy Storage Technologies: Synthesis of Anodes for Na-Ion Batteries from Biowaste
(MDPI, 2022-03-22)
Hard carbon is one of the most promising anode materials for sodium-ion batteries. In this work, new types of biomass-derived hard carbons were obtained through pyrolysis of different kinds of agro-industrial biowaste ...
Single-Ion Magnet and Photoluminescence Properties of Lanthanide(III) Coordination Polymers Based on Pyrimidine-4,6-Dicarboxylate
(MDPI, 2021-01-04)
Herein, we report the magnetic and photoluminescence characterization of coordination polymers (CP) built from the combination of lanthanide(III) ions, pyrimidine-4,6-dicarboxylate (pmdc) ligand and a co-ligand with formula ...
Ionothermal Synthesis of Cadmium Coordination Polymers: Ionic Liquid Effects on the Synthesis, Structural, and Thermal Characterization
(MDPI, 2019-11-09)
Ionothermal synthesis is a little used method for the preparation of coordination polymers. By this method, two cadmium compounds were synthesized, 1, with formula Cd-3(ox)F-2(Ina)(2) (Ina = isonicotinate) and 2, Cd(NO3)(2)(4,4 ...
Slow Magnetic Relaxation and Luminescent Properties of Mononuclear Lanthanide-Substituted Keggin-Type Polyoxotungstates with Compartmental Organic Ligands
(American Chemical Society, 2022-02-07)
The reaction of mid to late lanthanide ions with the N,N'-dimethyl-N,N'-bis(2-hydroxy-3-formyl-5-bromobenzyl)ethylene-diamine organic ligand and monolacunary Keggin type [alpha-SiW11O39]8- anion affords a series of ...
Synthesis, Structural Features and Physical Properties of a Family of Triply Bridged Dinuclear 3d-4f Complexes
(MDPI, 2021-02-05)
New dinuclear MII-LnIII complexes of general formulas [Cu(µ-L)(µ-OAc)Ln(NO3)2]·CH3CN·H2O (LnIII = Gd (1), Tb (2), Dy (3) and Er (4)), [Ni(CH3CN)(µ-L)(µ-OAc)Ln(NO3)2]·CH3CN (LnIII = Nd (5), Gd (6), Tb (7), Dy (8), Er (9) ...