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Now showing items 11-18 of 18
Metal-organic aerogels based on titanium(IV) for visible-light conducted CO2 photoreduction to alcohols
(Elsevier, 2022-12)
Metal-organic frameworks (MOFs) imply an appealing source of photocatalysts as they combine porosity with tailorable electronic properties and surface chemistry. Herein, we report a series of unprecedented metal-organic ...
An in solution adsorption characterization technique based on the response to an external magnetic field of porous paramagnetic materials: application on supramolecular metal–adenine frameworks containing heterometallic heptameric clusters
(Royal Society of Chemistry, 2023-01-18)
Herein we explore the opportunities arising from combining magnetic properties and porosity in metal–organic materials. In this sense, we have prepared an adenine based homometallic wheel-shaped heptameric [Cu7(μ-adenina ...
The Chemistry of zirconium/carboxylate clustering process: acidic conditions to promote carboxylate-unsaturated octahedral hexamers and pentanuclear species
(American Chemical Society, 2022-03-14)
Clustering chemistry is a key point in the design and synthesis of the secondary building units that comprise metal–organic frameworks (MOFs) based on group IV metals. In this work, the first stages of the zirconium-carboxylate ...
Thermochemical CO2 reduction catalyzed by homometallic and heterometallic nanoparticles generated from the thermolysis o supramolecularly assembled porous metal-adenine precursors
(American Chemical Society, 2023-10-09)
A family of unprecedented supramolecularly assembled porous metal–organic compounds (SMOFs), based on [Cu6M(μ-adeninato)6(μ3-OH)6(μ-H2O)6]2+ cations (MII: Cu, Co, Ni, and Zn) and different dicarboxylate anions (fumarate, ...
Copper(II)-porphyrin functionalized titanium(IV) metal-organic aerogels for the visible-light driven conversion of CO2 to alcohols
(Elsevier, 2023-08)
This manuscript covers the synthesis and characterization of a series of titanium based metal-organic aerogels (MOAs) functionalized with copper(II)-metalated porphyrins for their application in visible-light-driven carbon ...
A straightforward route to obtain zirconium based metal-organic gel
(Elsevier, 2019-04-12)
Zirconium based metal-organic gels are obtained through a rapid method at room temperature, employing green solvents, in which the role of water is important. These porous materials, decorated with Brønsted acid sites, ...
Adenine nucleobase directed supramolecular architectures based on ferrimagnetic heptanuclear copper(II) entities and benzenecarboxylate anions
(Elsevier, 2019-10-05)
Two planar organic anions, benzoate and benzene-1,4-dicarboxylate (terephthalate), have been selected as potential π-stacking intercalators among ferrimagnetic [Cu7(μ-adeninato)6(μ3-OH)6(μ-H2O)6]2+ heptameric discrete ...
Isoreticular chemistry and applications of supramolecularly assembled copper−adenine porous materials
(American Chemical Society, 2023-11-01)
The useful concepts of reticular chemistry, rigid and predictable metal nodes together with strong and manageable covalent interactions between metal centers and organic linkers, have made the so-called metal–organic ...