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Incommensurate crystal structure, thermal expansion study and magnetic properties of (dimethylimidazolium)2[Fe2Cl6(μ-O)]
(IOP, 2020-01-01)
A thorough characterization of the title compound, (dimim)(2)[Fe2Cl6(mu-O)], consisting of a (mu-oxido)-bridged binuclear iron(III) complex and 1,3-dimethylimiazolium (dimim) cation, has been performed using a wide range ...
Innovative Microstructural Transformation upon CO2 Supercritical Conditions on Metal-Nucleobase Aerogel and Its Use as Effective Filler for HPLC Biomolecules Separation
(MDPI, 2022-02-17)
This work contributes to enlightening the opportunities of the anisotropic scheme of non-covalent interactions present in supramolecular materials. It provides a top-down approach based on their selective disruption that ...
Single-Crystal-to-Single-Crystal Cluster Transformation in a Microporous Molybdoarsenate(V)-Metalorganic Framework
(American Chemical Society, 2021-09-21)
[EN]The hybrid compound [Cu(cyclam)(H2O)(2)](0.5)[{Cu(cyclam)}(1.5){B-H2As2Mo6O26(H2O)}].9H(2)O (1) (cyclam = 1,4,8,11- tetraazacyclotetradecane) was synthesized in aqueous solution by reacting the {Cu(cyclam)}(2+) complex ...
Aerogels of 1D Coordination Polymers: From a Non-Porous Metal-Organic Crystal Structure to a Highly Porous Material
(MDPI, 2016-01-15)
The processing of an originally non- porous 1D coordination polymer as monolithic gel, xerogel and aerogel is reported as an alternative method to obtain novel metal- organic porous materials, conceptually different to ...
Slot-Die Process of a Sol–Gel Photocatalytic Porous Coating for Large-Area Fabrication of Functional Architectural Glass
(MDPI, 2021-06-06)
The slot-die process is an appealing technology for the fabrication of coatings on large-area substrates. However, its application on the production of photocatalytic coatings based on sol–gel formulations remains virtually ...
Porous TiO2 thin film-based photocatalytic windows for an enhanced operation of optofluidic microreactors in CO2 conversion
(Elsevier, 2021-06-25)
[EN] Using a photocatalytic window can simplify the design of an optofluidic microreactor, providing also a more straightforward operation. Therefore, the development of TiO2coatings on glass substrates seems appealing, ...
Ferromagnetic supramolecular metal-organic frameworks for active capture and magnetic sensing of emerging drug pollutants
(Elsevier ; Cell Press, 2021-05-19)
[EN] Capture and sensing of emerging pollutants is one of the increasing environmental concerns due to the adverse ecological and human health effects. Here, we report the synthesis of a supramolecular metal-organic framework ...
A Lamellar Zn-Based Coordination Polymer Showing Increasing Photoluminescence upon Dehydration
(MDPI, 2023-07-25)
The present study reports on a 2D lamellar coordination polymer (CP) of {[Zn(µ3-pmdc)(H2O)]·H2O}n formula (pmdc = pyrimidine-4,6-dicarboxylate). This CP is synthesized under an appropriate acid-base reaction between the ...
Single-Ion Magnet and Photoluminescence Properties of Lanthanide(III) Coordination Polymers Based on Pyrimidine-4,6-Dicarboxylate
(MDPI, 2021-01-04)
Herein, we report the magnetic and photoluminescence characterization of coordination polymers (CP) built from the combination of lanthanide(III) ions, pyrimidine-4,6-dicarboxylate (pmdc) ligand and a co-ligand with formula ...
Copper(II) invigorated EHU-30 for continuous electroreduction of CO2 into value-added chemicals
(Nature, 2022-05-20)
The doping of zirconium based EHU-30 and EHU-30-NH2 metal-organic frameworks with copper(II) yielded a homogeneous distribution of the dopant with a copper/zirconium ratio of 0.04-0.05. The doping mechanism is analysed by ...