Search
Now showing items 1-10 of 22
A synergistic exploitation to produce high-voltage quasi-solid-state lithium metal batteries
(Nature Research, 2021-09-30)
[EN]The energy content increase is of paramount importance for the development of future Li-based batteries. Here, the authors propose a gel polymer electrolyte in combination with a positive electrode comprising of a ...
Synthetic control over polymorph formation in the d-band semiconductor system FeS2
(Royal Society of Chemistry, 2021-10-27)
[EN]Pyrite, also known as fool's gold is the thermodynamic stable polymorph of FeS2. It is widely considered as a promising d-band semiconductor for various applications due to its intriguing physical properties. Marcasite ...
Prediction of Anti-Glioblastoma Drug-Decorated Nanoparticle Delivery Systems Using Molecular Descriptors and Machine Learning
(MDPI, 2021-10-26)
The theoretical prediction of drug-decorated nanoparticles (DDNPs) has become a very important task in medical applications. For the current paper, Perturbation Theory Machine Learning (PTML) models were built to predict ...
Kinetic Studies of Acetyl Group Migration between the Saccharide Units in an Oligomannoside Trisaccharide Model Compound and a Native Galactoglucomannan Polysaccharide
(Wiley, 2021-10-13)
Acyl group migration is a fundamental phenomenon in carbohydrate chemistry, recently shown to take place also between two non-adjacent hydroxyl groups, across the glycosidic bond, in a beta-(1 -> 4)-linked mannan trisaccharide ...
Selective C-13-Labels on Repeating Glycan Oligomers to Reveal Protein Binding Epitopes through NMR: Polylactosamine Binding to Galectins
(Wiley, 2021-08-16)
A combined chemo-enzymatic synthesis/NMR-based methodology is presented to identify, in unambiguous manner, the distinctive binding epitope within repeating sugar oligomers when binding to protein receptors. The concept ...
Dicopper(II)-EDTA Chelate as a Bicephalic Receptor Model for a Synthetic Adenine Nucleoside
(MDPI, 2021-05-02)
In the extensive field of metal ions, their interactions with nucleic acids, and their constituents, the main aim of this work is to develop a metal chelate suitable to recognize two molecules of an adenine nucleoside. For ...
Single-Crystal-to-Single-Crystal Cluster Transformation in a Microporous Molybdoarsenate(V)-Metalorganic Framework
(American Chemical Society, 2021-09-21)
[EN]The hybrid compound [Cu(cyclam)(H2O)(2)](0.5)[{Cu(cyclam)}(1.5){B-H2As2Mo6O26(H2O)}].9H(2)O (1) (cyclam = 1,4,8,11- tetraazacyclotetradecane) was synthesized in aqueous solution by reacting the {Cu(cyclam)}(2+) complex ...
Direct Arylation in the Presence of Palladium Pincer Complexes
(MDPI, 2021-07-20)
Direct arylation is an atom-economical alternative to more established procedures such as Stille, Suzuki or Negishi arylation reactions. In comparison with other palladium sources and ligands, the use of palladium pincer ...
Transannular Enantioselective (3 + 2) Cycloaddition of Cycloalkenone Hydrazones under Bronsted Acid Catalysis.
(American Chemical Society, 2021-11-19)
[EN]Hydrazones derived from cycloalkenones undergo an enantioselective transannular formal (3 + 2) cycloaddition catalyzed by a chiral phosphoric acid. The reaction provides high yields and excellent stereocontrol in the ...
Porous TiO2 thin film-based photocatalytic windows for an enhanced operation of optofluidic microreactors in CO2 conversion
(Elsevier, 2021-06-25)
[EN] Using a photocatalytic window can simplify the design of an optofluidic microreactor, providing also a more straightforward operation. Therefore, the development of TiO2coatings on glass substrates seems appealing, ...