1H-Imidazol-4(5H)-ones and thiazol-4(5H)-ones as emerging pronucleophiles in asymmetric catalysis
dc.contributor.author | Mielgo Vicente, María Antonia ![]() | |
dc.contributor.author | Palomo Nicolau, Claudio | |
dc.date.accessioned | 2018-03-16T09:09:25Z | |
dc.date.available | 2018-03-16T09:09:25Z | |
dc.date.issued | 2016-05-09 | |
dc.identifier.citation | Beilstein Journal of Organic Chemistry 12 : 918-936 (2016) | es_ES |
dc.identifier.issn | 1860-5397 | |
dc.identifier.uri | http://hdl.handle.net/10810/25727 | |
dc.description.abstract | Asymmetric catalysis represents a very powerful tool for the synthesis of enantiopure compounds. In this context the main focus has been directed not only to the search for new efficient chiral catalysts, but also to the development of efficient pronucleophiles. This review highlights the utility and first examples of 1H-imidazol-4(5H)-ones and thiazol-4(5H)-ones as pronucleophiles in catalytic asymmetric reactions. | es_ES |
dc.description.sponsorship | The authors acknowledge the University of the Basque Country UPV/EHU (UFI 11/22), the Basque Government (Grant No IT-628-13) and the Ministerio de Economia y Competitividad (MEC, Grant CTQ2013-47925-C2-1-P), Spain for financial support. | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | Beilstein Institut | es_ES |
dc.relation | info:eu-repo/grantAgreement/MINECO/CTQ2013-47925-C2-1-P | es_ES |
dc.rights | info:eu-repo/semantics/openAccess | es_ES |
dc.rights.uri | http://creativecommons.org/licenses/by/3.0/es/ | * |
dc.subject | asymmetric catalysis | es_ES |
dc.subject | bifunctional catalysts | es_ES |
dc.subject | 1H-imidazol-4(5H)-ones | es_ES |
dc.subject | pronucleophiles thiazol-4(5H)-ones | es_ES |
dc.subject | alpha-amino-acids | es_ES |
dc.subject | carbon bond formation | es_ES |
dc.subject | enantioselective Michael addition | es_ES |
dc.subject | stereoselective-synthesis | es_ES |
dc.subject | quaternary stereocenters | es_ES |
dc.subject | 1,4-addition reaction | es_ES |
dc.subject | chiral guanidines | es_ES |
dc.subject | gamma-addition | es_ES |
dc.subject | soft enolization | es_ES |
dc.subject | thiourea organocatalysts | es_ES |
dc.title | 1H-Imidazol-4(5H)-ones and thiazol-4(5H)-ones as emerging pronucleophiles in asymmetric catalysis | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.rights.holder | This is an Open Access article under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0), whichpermits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. | es_ES |
dc.rights.holder | Atribución 3.0 España | * |
dc.relation.publisherversion | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4902076/ | es_ES |
dc.identifier.doi | 10.3762/bjoc.12.90 | |
dc.departamentoes | Química orgánica I | es_ES |
dc.departamentoeu | Kimika organikoa I | es_ES |
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