A redox-active radical as an effective nanoelectronic component: stability and electrochemical tunnelling spectroscopy in ionic liquids

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Date
2016-10-28
Author
Rudnev, Alexander V.
Franco, Carlos
Crivillers, Núria
Seber, Gonca
Droghetti, Andrea
Rungger, Ivan
Pobelov, Ilya V.
Veciana, Jaume
Mas-Torrent, Marta
Rovira, Concepció
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Physical Chemistry Chemical Physics 18(40) : 27733-27737 (2016)
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http://hdl.handle.net/10810/25828
Abstract
A redox-active persistent perchlorotriphenylmethyl (PTM) radical chemically linked to gold exhibits stable electrochemical activity in ionic liquids. Electrochemical tunnelling spectroscopy in this medium demonstrates that the PTM radical shows a highly effective redox-mediated current enhancement, demonstrating its applicability as an active nanometer-scale electronic component.
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This article is licensed under a Creative Commons Attribution 3.0 Unported (CC BY 3.0)
Except where otherwise noted, this item's license is described as This article is licensed under a Creative Commons Attribution 3.0 Unported (CC BY 3.0)