dc.contributor.author | García Valdivia, Antonio A. | |
dc.contributor.author | Zabala Lekuona, Andoni | |
dc.contributor.author | Ramírez Rodríguez, Gloria B. | |
dc.contributor.author | Delgado López, José M. | |
dc.contributor.author | Fernández, Belén | |
dc.contributor.author | Cepeda Ruiz, Javier | |
dc.contributor.author | Rodríguez Diéguez, Antonio | |
dc.date.accessioned | 2020-11-20T12:13:05Z | |
dc.date.available | 2020-11-20T12:13:05Z | |
dc.date.issued | 2020-08-14 | |
dc.identifier.citation | CrystEngComm 22(30) : 5086-5095 (2020) | es_ES |
dc.identifier.issn | 1466-8033 | |
dc.identifier.uri | http://hdl.handle.net/10810/48465 | |
dc.description.abstract | We report the formation of five novel multifunctional coordination polymers based on 1H-indazole-4-carboxylic acid (HL). To the best of our knowledge, these complexes are the first examples of coordination compounds constructed with this interesting ligand. These materials were synthesized by solvothermal routes, possess different 2D-structures and show interesting magnetic properties due to the copper compound showing an unusual spin-canted effect while the anisotropic cobalt material behaves as a field-induced single molecule magnet. MTT assays performed on human embryonic kidney (HEK293) and mouse skin melanoma (B16-F10) cell lines indicated that the Cd-based compound was the only one exhibiting dose-dependent toxicity on B16-F10 cells, most likely due to the release of toxic Cd(ii). Cadmium and zinc polymers exhibit interesting luminescence properties. The fact that zinc polymers did not exhibit inherent toxicity against both cancer and non-cancerous cells make this new family an excellent candidate for further investigation in the field of luminescent materials with biomedical applications. | es_ES |
dc.description.sponsorship | Financial support was given by the Junta de Andalucia (Spain) (FQM-394 and FQM-1484), the Red Guipuzcoana de Ciencia, Tecnologia e Innovacion (OF218/2018), the University of the Basque Country (GIU 17/13), the Gobierno Vasco/Eusko Jaurlaritza (IT1005-16), the Spanish Ministry of Science, Innovation and Universities (MCIU/AEI/FEDER, UE) (PGC2018-102052-A-C22, PGC2018-102052-B-C21), and Junta de Andalucia (FQM-394 and FQM-1484). The authors thank the technical and human support provided by the SGIker of UPV/EHU and European funding (ERDF and ESF). A. Z.-L. is grateful to the Government of the Basque Country for the predoctoral fellowship. J. M. D.-L and G. B. R.-R. acknowledge the FEDER/MCIU/AEI for their Ramon y Cajal (RYC-2016-21042) and Juan de la Cierva (JdC-2017) fellowships, respectively. | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | Royal Society of Chemistry | es_ES |
dc.relation | info:eu-repo/grantAgreement/MCIU/PGC2018-102052-B-C21 | es_ES |
dc.relation | info:eu-repo/grantAgreement/MCIU/PGC2018-102052-A-C22 | es_ES |
dc.rights | info:eu-repo/semantics/openAccess | es_ES |
dc.rights.uri | http://creativecommons.org/licenses/by/3.0/es/ | * |
dc.subject | organic frameworks | es_ES |
dc.subject | complexes | es_ES |
dc.subject | relaxation | es_ES |
dc.subject | cluster | es_ES |
dc.subject | zinc | es_ES |
dc.title | 2D-Coordination polymers based on 1H-indazole-4-carboxylic acid and transition metal ions: magnetic, luminescence and biological properties | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.rights.holder | This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Material from this article can be used in other publications provided that the correct acknowledgement is given with the reproduced material. | es_ES |
dc.rights.holder | Atribución 3.0 España | * |
dc.relation.publisherversion | https://pubs.rsc.org/en/content/articlelanding/2020/CE/D0CE00544D#!divAbstract | es_ES |
dc.identifier.doi | 10.1039/d0ce00544d | |
dc.departamentoes | Química aplicada | es_ES |
dc.departamentoeu | Kimika aplikatua | es_ES |