Development of Kraft Lignin Chemically Modified as a Novel Crosslinking Agent for the Synthesis of Active Hydrogels
dc.contributor.author | Rico-García, Diana | |
dc.contributor.author | Guerrero-Ramírez, Luis Guillermo | |
dc.contributor.author | Cajero-Zul, Leonardo Ramses | |
dc.contributor.author | Orozco-Guareño, Euologio | |
dc.contributor.author | Figueroa-Ochoa, Edgar Benjamin | |
dc.contributor.author | Gutiérrez-Saucedo, Ramon Alejandro | |
dc.contributor.author | Pérez Álvarez, Leyre | |
dc.contributor.author | Vilas Vilela, José Luis | |
dc.contributor.author | Hernandez-Olmos, Saira Lizette | |
dc.date.accessioned | 2021-05-17T08:47:21Z | |
dc.date.available | 2021-05-17T08:47:21Z | |
dc.date.issued | 2021-04-28 | |
dc.identifier.citation | Applied Sciences 11(9) : (2021) // Article ID 4012 | es_ES |
dc.identifier.issn | 2076-3417 | |
dc.identifier.uri | http://hdl.handle.net/10810/51408 | |
dc.description.abstract | In this research a chemical modification of kraft lignin was carried out using a basic nucleophilic substitution reaction (NSA) in order to functionalize it as a novel crosslinking agent for the synthesis of active hydrogels. The chemical modification success of the synthesized crosslinker was demonstrated by using several techniques such as volumetry probes, FTIR, 1H-NMR and DSC. Thus, the obtained materials were employed during the synthesis of acrylic acid-based hydrogels, due to its high-water absorption capacity to evaluate their retention potential of heavy metal ions. Characterization of the active hydrogels were performed by FTIR and SEM, showing the specific signals corresponding to the base monomers into the polymer skeleton and the efficiency of modified kraft lignin as a novel crosslinking agent. Additionally, to demonstrate the potential use of these hydrogels in wastewater treatment, metal ions adsorption experiments were conducted, showing adsorption percentages higher than 90% and 80% for Pb2+ and Cu2+, respectively. | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | MDPI | es_ES |
dc.rights | info:eu-repo/semantics/openAccess | es_ES |
dc.rights.uri | http://creativecommons.org/licenses/by/3.0/es/ | |
dc.subject | novel crosslinking | es_ES |
dc.subject | active hydrogels | es_ES |
dc.subject | adsorption experiments | es_ES |
dc.title | Development of Kraft Lignin Chemically Modified as a Novel Crosslinking Agent for the Synthesis of Active Hydrogels | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.date.updated | 2021-05-13T14:32:10Z | |
dc.rights.holder | 2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). | es_ES |
dc.relation.publisherversion | https://www.mdpi.com/2076-3417/11/9/4012/htm | es_ES |
dc.identifier.doi | 10.3390/app11094012 | |
dc.departamentoes | Química física | |
dc.departamentoeu | Kimika fisikoa |
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Except where otherwise noted, this item's license is described as 2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).