dc.contributor.author | Veneranda, Marco | |
dc.contributor.author | Prieto Taboada, Nagore | |
dc.contributor.author | Carrero Hernández, José Antonio | |
dc.contributor.author | Costantini, Ilaria | |
dc.contributor.author | Larrañaga Varga, Aitor | |
dc.contributor.author | Castro Ortiz de Pinedo, Kepa | |
dc.contributor.author | Arana Momoitio, Gorka | |
dc.contributor.author | Madariaga Mota, Juan Manuel | |
dc.date.accessioned | 2021-06-10T08:44:40Z | |
dc.date.available | 2021-06-10T08:44:40Z | |
dc.date.issued | 2021-05-24 | |
dc.identifier.citation | Scientific Reports 11(1) : (2021) // Article ID 10789 | es_ES |
dc.identifier.issn | 2045-2322 | |
dc.identifier.uri | http://hdl.handle.net/10810/51823 | |
dc.description.abstract | The conservation of iron objects exposed to marine aerosol is threatened by the formation of akaganeite, a highly unstable Cl-bearing corrosion phase. As akaganeite formation is responsible of the exfoliation of the rust layer, chlorides trigger a cyclic alteration phenomenon that often ends with the total consumption of the iron core. To prevent this degradation process, movable iron elements (e.g. archaeometallurgical artefacts) are generally immersed in alkaline dechlorination baths. Aiming to transfer this successful method to the treatment of immovable iron objects, we propose the in-situ application of alkaline solutions through the use of highly absorbent wraps. As first step of this novel research line, the present work defines the best desalination solution to be used and optimizes its extraction yield. After literature review, a screening experimental design was performed to understand the single and synergic effects of common additives used for NaOH baths. Once the most effective variables were selected, an optimization design was carried out to determine the optimal conditions to be set during treatment. According to the experimental work here presented, the use of 0.7 M NaOH solutions applied at high temperatures (above 50 °C) is recommended. Indeed, these conditions enhance chloride extraction and iron leaching inhibition, while promoting corrosion stabilization. | es_ES |
dc.description.sponsorship | This work has been funded by the DEMORA project (Grant No. PID2020-113391GB-I00), funded by the Spanish Agency for Research (through the Spanish Ministry of Science and Innovation, MICINN, and the European Regional Development Fund, FEDER). | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | Springer | es_ES |
dc.rights | info:eu-repo/semantics/openAccess | es_ES |
dc.rights.uri | http://creativecommons.org/licenses/by/3.0/es/ | * |
dc.subject | iron objects | es_ES |
dc.subject | marine aerosol | es_ES |
dc.subject | akaganeite | es_ES |
dc.subject | exfoliation of the rust layer | es_ES |
dc.subject | alkaline solutions | es_ES |
dc.subject | desalination | es_ES |
dc.subject | NaOH baths | es_ES |
dc.subject | corrosion stabilization | es_ES |
dc.title | Development of a Novel Method for the In-Situ Dechlorination of Immovable Iron Elements: Optimization of Cl- Extraction Yield Through Experimental Design | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.rights.holder | This article is licensed under a Creative Commons Attribution 4.0 International License (CC BY 4.0) | es_ES |
dc.rights.holder | Atribución 3.0 España | * |
dc.relation.publisherversion | https://www.nature.com/articles/s41598-021-90006-y | es_ES |
dc.identifier.doi | 10.1038/s41598-021-90006-y | |
dc.departamentoes | Química analítica | es_ES |
dc.departamentoes | Química aplicada | es_ES |
dc.departamentoeu | Kimika analitikoa | es_ES |
dc.departamentoeu | Kimika aplikatua | es_ES |