dc.contributor.author | Dissem, Nour | |
dc.contributor.author | Artetxe Arretxe, Beñat | |
dc.contributor.author | San Felices Mateos, Leire | |
dc.contributor.author | Beobide Pacheco, Garikoitz | |
dc.contributor.author | Castillo García, Oscar | |
dc.contributor.author | Ruiz Bilbao, Estibaliz | |
dc.contributor.author | Lezama Diago, Luis María | |
dc.contributor.author | Vivanco Ruiz, María del Mar | |
dc.contributor.author | Haddad, Amor | |
dc.contributor.author | Gutiérrez Zorrilla López, Juan Manuel | |
dc.date.accessioned | 2021-11-22T09:28:22Z | |
dc.date.available | 2021-11-22T09:28:22Z | |
dc.date.issued | 2021-09-21 | |
dc.identifier.citation | Inorganic chemistry 60(19) : 14913-14923 (2021) | es_ES |
dc.identifier.issn | 0020-1669 | |
dc.identifier.issn | 1520-510X | |
dc.identifier.uri | http://hdl.handle.net/10810/53918 | |
dc.description.abstract | [EN]The hybrid compound [Cu(cyclam)(H2O)(2)](0.5)[{Cu(cyclam)}(1.5){B-H2As2Mo6O26(H2O)}].9H(2)O (1) (cyclam = 1,4,8,11- tetraazacyclotetradecane) was synthesized in aqueous solution by reacting the {Cu(cyclam)}(2+) complex with a mixture of heptamolybdate and an arsenate(V) source. Crystal packing of 1 exhibits a supramolecular open-framework built of discrete covalent molybdoarsenate/metalorganic units and additional [Cu(cyclam)-(H2O)(2)](2+) cations, the stacking of which generates squarelike channels parallel to the z axis with an approximate cross section of 10 x 11 A(2) where all the hydration water molecules are hosted. Thermal evacuation of solvent molecules yields a new anhydrous crystalline phase, but compound 1 does not preserve its singlecrystalline nature upon heating. However, when crystals are dehydrated under vacuum, they undergo a structural transformation that proceeds via a single-crystal-to-single-crystal pathway, leading to the anhydrous phase [{Cu(cyclam)}(2)(A-H2As2Mo6O26)] (2). Total dehydration results in important modifications within the inorganic cluster skeleton which reveals an unprecedented solid-state B to A isomerization of the polyoxoanion. This transition also involves changes in the CuII bonding scheme that lead to covalent cluster/metalorganic layers by retaining the open-framework nature of 1. Compound 2 adsorbs ambient moisture upon air exposure, but it does not revert back to 1, and the hydrated phase [{Cu(cyclam)}(2)(A-H2As2Mo6O26)]center dot 6H(2)O (2h) is obtained instead. Structural variations between 1 and 2 are reflected in electron paramagnetic resonance spectroscopy measurements, and the permanent microporosity of 2 provides interesting functionalities to the system such as the selective adsorption of gaseous CO2 over N-2. | es_ES |
dc.description.sponsorship | This work was funded by Eusko Jaurlaritza/Gobierno Vasco (EJ/GV, Grants IT-1291-19 and KK-2020/00008, together with a predoctoral fellowship to E.R.-B.), Ministerio de Economia, Industria y Competitividad (Grant MAT2017-89553-P), and University of Tunis El Manar (predoctoral fellowship to N.D. including a research stay at UPV/EHU). | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | American Chemical Society | es_ES |
dc.relation | info:eu-repo/grantAgreement/MINECO/MAT2017-89553-P | es_ES |
dc.rights | info:eu-repo/semantics/openAccess | es_ES |
dc.rights.uri | http://creativecommons.org/licenses/by/3.0/es/ | * |
dc.subject | metal-organic framework | es_ES |
dc.subject | structural transformation | es_ES |
dc.subject | ionic-crystals | es_ES |
dc.subject | complexes | es_ES |
dc.subject | anions | es_ES |
dc.subject | water | es_ES |
dc.subject | SCSC | es_ES |
dc.title | Single-Crystal-to-Single-Crystal Cluster Transformation in a Microporous Molybdoarsenate(V)-Metalorganic Framework | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.rights.holder | © 2021 The Authors. Attribution 4.0 International (CC BY 4.0) | es_ES |
dc.rights.holder | Atribución 3.0 España | * |
dc.relation.publisherversion | https://pubs.acs.org/doi/10.1021/acs.inorgchem.1c02276 | es_ES |
dc.identifier.doi | 10.1021/acs.inorgchem.1c02276 | |
dc.departamentoes | Química Orgánica e Inorgánica | es_ES |
dc.departamentoeu | Kimika Organikoa eta Ez-Organikoa | es_ES |