dc.contributor.author | Gómez López, Álvaro ![ORCID](/themes/Mirage2//images/orcid_16x16.png) | |
dc.contributor.author | Ayensa Serrano, Naroa | |
dc.contributor.author | Grignard, Bruno | |
dc.contributor.author | Irusta Maritxalar, María Lourdes | |
dc.contributor.author | Calvo, Iñigo | |
dc.contributor.author | Müller Sánchez, Alejandro Jesús ![ORCID](/themes/Mirage2//images/orcid_16x16.png) | |
dc.contributor.author | Detrembleur, Christophe | |
dc.contributor.author | Sardon Muguruza, Haritz | |
dc.date.accessioned | 2022-09-07T10:35:55Z | |
dc.date.available | 2022-09-07T10:35:55Z | |
dc.date.issued | 2022 | |
dc.identifier.citation | ACS Polymers Au 2(3) : 194-207 (2022) | es_ES |
dc.identifier.issn | 2694-2453 | |
dc.identifier.uri | http://hdl.handle.net/10810/57459 | |
dc.description.abstract | [EN] Poly(hydroxy urethane)s (PHUs) based on 5-membered cyclic carbonates have emerged as sustainable alternatives to conventional isocyanate-based polyurethanes. However, while from the point of view of sustainability they represent an improvement, their properties are still not competitive with conventional polyurethanes. In this work, the potential of PHUs as reversible hot-melt adhesives is discussed. We found that with a judicious choice of reagents (ie., the dicyclic carbonate and diamine), the detrimental hydrogen bonding between the soft segment of the chains and the pendant hydroxyl groups was partially avoided, thus imparting PHUs with hot-melt adhesion properties (i.e., adhesion at elevated temperatures and cohesiveness at a temperature lower than T-g/T-m). The importance of a balanced hard to soft segment ratio, along with the relevance of the chain extender in the final properties, is highlighted. Addition of aliphatic diamines (HMDA, 1,12-DAD) resulted in rubbery materials, while the employment of cydoaliphatic (CBMA) or aromatic ones (MXDA, PXDA) led to materials with hot-melt adhesive properties. The thermoreversibility of all compositions was assessed by rebonding specimens after lap-shear tests. Lap-shear strength values that were comparable to the virgin adhesives were observed. The breaking and reformation of hydrogen bonding interactions was demonstrated by FTIR measurements at different temperatures, as well as by rheological frequency sweep experiments. In order to mitigate the negative impact of the low molar mass PHUs and to enhance the service temperature of the adhesives, a hybrid PHU was prepared by adding a small amount of an epoxy resin, which acts as a cross-linker. These hybrid PHUs maintain the thermoreversibility displayed by thermoplastic PHUs while providing better adhesion at elevated temperatures. We believe that this work provides some important insights into the design of PHU-based hot-melt adhesives. | es_ES |
dc.description.sponsorship | The authors would like to acknowledge the technical and human support provided by SGIker (UPV/EHU and ERDF, EU). A.G.-L. acknowledges the University of the Basque Country for the predoctoral fellowship received to carry out this work. The authors would also like to acknowledge the technical support provided by Amaia Agirre for the GPC analysis. ORIBAY Group Automotive also wants to acknowledge the HAZITEK program for the final support of the project n degrees ZL-2019/00193. This project has been partly supported by the European Union's Horizon 2020 research and innovation program under Marie Sklodowska-Curie grant agreement No. 955700. C.D. thanks FNRS for financial support. The authors of Liege thank the "Fonds National pour la Recherche Scientifique" (F.R.S.-FNRS) and the Fonds Wetenschappelijk Onderzoek-Vlaanderen (FWO) for financial support in the frame of the EOS project n degrees O019618F (ID EOS: 30902231). C.D. is F.R.S.-FNRS Research Director. | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | American Chemical Society | es_ES |
dc.relation | info:eu-repo/grantAgreement/EC/H2020/955700 | es_ES |
dc.rights | info:eu-repo/semantics/openAccess | es_ES |
dc.rights.uri | http://creativecommons.org/licenses/by/3.0/es/ | * |
dc.subject | non-isocyanate polyurethanes | es_ES |
dc.subject | poly(hydroxy urethane)s | es_ES |
dc.subject | hot-melt | es_ES |
dc.subject | adhesives | es_ES |
dc.subject | sustainability | es_ES |
dc.subject | green chemistry | es_ES |
dc.title | Enhanced and Reusable Poly(hydroxy urethane)-Based Low Temperature Hot-Melt Adhesives | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.rights.holder | © 2022 The Authors. Published by American Chemical Society.
Attribution 4.0 International (CC BY 4.0) | es_ES |
dc.rights.holder | Atribución 3.0 España | * |
dc.relation.publisherversion | https://pubs.acs.org/doi/10.1021/acspolymersau.1c00053 | es_ES |
dc.identifier.doi | 10.1021/acspolymersau.1c00053 | |
dc.contributor.funder | European Commission | |
dc.departamentoes | Polímeros y Materiales Avanzados: Física, Química y Tecnología | es_ES |
dc.departamentoeu | Polimero eta Material Aurreratuak: Fisika, Kimika eta Teknologia | es_ES |