dc.contributor.author | Echenique Errandonea, Estitxu | |
dc.contributor.author | Mendes, Ricardo F. | |
dc.contributor.author | Figueira, Flavio | |
dc.contributor.author | Choquesillo Lazarte, Duane | |
dc.contributor.author | Beobide Pacheco, Garikoitz | |
dc.contributor.author | Cepeda Ruiz, Javier | |
dc.contributor.author | Ananias, Duarte | |
dc.contributor.author | Rodríguez Diéguez, Antonio | |
dc.contributor.author | Almeida Paz, Filipe A. | |
dc.contributor.author | Seco Botana, José Manuel | |
dc.date.accessioned | 2022-11-03T17:19:29Z | |
dc.date.available | 2022-11-03T17:19:29Z | |
dc.date.issued | 2022-08 | |
dc.identifier.citation | Inorganic Chemistry 61(33) : 12977-12990 (2022) | es_ES |
dc.identifier.issn | 0020-1669 | |
dc.identifier.issn | 1520-510X | |
dc.identifier.uri | http://hdl.handle.net/10810/58244 | |
dc.description.abstract | Herein, we describe and study a new family of isostructural multifunctional metal-organic frameworks (MOFs) with the formula {[Ln(5)L(6)(OH)(3)(DMF)(3)]center dot 5H(2)O} n (where (H2L) is 3-amino-4-hydroxybenzoic acid ligand) for magnetism and photoluminescence. Interestingly, three of the materials (Dy-, Er-, and Yb-based MOFs) present singlemolecule magnet (SMM) behavior derived from the magnetic anisotropy of the lanthanide ions as a consequence of the adequate electronic distribution of the coordination environment. Additionally, photoluminescence properties of the ligand in combination with Eu and Tb counterparts were studied, including the heterometallic Eu-Tb mixed MOF that shows potential as ratiometric luminescent thermometers. Finally, the porous nature of the framework allowed showing the CO2 sorption capacity. | es_ES |
dc.description.sponsorship | E.E. is grateful to the Government of the Basque Country for the predoctoral fellowship and R.F.M. to the Junior Research Position CEECIND/ 00553/2017. The research contract of FF (REF-168-89-ARH/2018) is funded by national funds (OE), through FCT, in the scope of the framework contract foreseen in nos. 4, 5, and 6 of article 23 of the Decree-Law 57/2016, of 29 August, changed by Law 57/2017, of 19 July. This work was developed within the scope of the projects given by the Spanish Ministry of Science, Innovation and Universities (MCIU/AEI/ FEDER, UE) (PGC2018-102052-A-C22, PGC2018-102052-BC21, and PID2019-108028GB-C21), Gobierno Vasco/Eusko Jaurlaritza (IT1310-19 and IT1291-19), Junta de Andalucia (FQM-394), University of the Basque Country (GIU 20/028), and CICECO-Aveiro Institute of Materials (UIDB/50011/ 2020 and UIDP/50011/2020). | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | American Chemical Society | es_ES |
dc.relation | info:eu-repo/grantAgreement/MICIU/PGC2018-102052-A-C22 | es_ES |
dc.relation | info:eu-repo/grantAgreement/MICIU/PGC2018-102052-B-C21 | es_ES |
dc.relation | info:eu-repo/grantAgreement/MICINN/PID2019-108028GB-C21 | es_ES |
dc.rights | info:eu-repo/semantics/openAccess | es_ES |
dc.rights.uri | http://creativecommons.org/licenses/by/3.0/es/ | * |
dc.subject | crystal structures | es_ES |
dc.subject | gas adsorption | es_ES |
dc.subject | coordination polymers | es_ES |
dc.subject | ralaxation | es_ES |
dc.subject | ytterbium | es_ES |
dc.subject | capture | es_ES |
dc.subject | phosphonate | es_ES |
dc.subject | separation | es_ES |
dc.subject | design | es_ES |
dc.title | Multifunctional Lanthanide-Based Metal-Organic Frameworks Derived from 3-Amino-4-hydroxybenzoate: Single-Molecule Magnet Behavior, Luminescent Properties for Thermometry, and CO2 Adsorptive Capacity | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.rights.holder | © 2022 The Authors. Published by American Chemical Society under a Creative Commons license Attribution 4.0 International (CC BY 4.0) | es_ES |
dc.rights.holder | Atribución 3.0 España | * |
dc.relation.publisherversion | https://pubs.acs.org/doi/10.1021/acs.inorgchem.2c00544 | es_ES |
dc.identifier.doi | 10.1021/acs.inorgchem.2c00544 | |
dc.departamentoes | Química Orgánica e Inorgánica | es_ES |
dc.departamentoes | Química aplicada | es_ES |
dc.departamentoeu | Kimika Organikoa eta Ez-Organikoa | es_ES |
dc.departamentoeu | Kimika aplikatua | es_ES |