dc.contributor.author | Carral Menoyo, Asier | |
dc.contributor.author | Misol, Alexander | |
dc.contributor.author | Gómez Redondo, Marcos | |
dc.contributor.author | Sotomayor Anduiza, María Nuria | |
dc.contributor.author | Lete Expósito, María Esther | |
dc.date.accessioned | 2023-11-20T13:10:03Z | |
dc.date.available | 2023-11-20T13:10:03Z | |
dc.date.issued | 2019-01-14 | |
dc.identifier.citation | The Journal of Organic Chemistry 84(4) : 2048-2060(2019) | es_ES |
dc.identifier.issn | 0022-3263 | |
dc.identifier.issn | 1520-6904 | |
dc.identifier.uri | http://hdl.handle.net/10810/63062 | |
dc.description.abstract | The intramolecular Pd(II)-catalyzed alkenylation of aryl homoallyl ethers constitutes a mild,
versatile, and efficient procedure for the synthesis of highly and diversely substituted chromanes, and
2H-chromenes. The use of p-TsOH as additive allows more efficient reactions that could be carried out
a room temperature in most cases. The procedure has a wide scope, allowing the synthesis of
alkylidenechromanes and 2H-chromenes substituted at C-2 or C-3 of the chromene moiety, thus
accessing relevant flavenes and isoflavenes, and even coumarins, in high yields (59 to 91%, 32
examples) | es_ES |
dc.description.sponsorship | Ministerio de Economía y Competitividad (CTQ2016-74881-P) // Gobierno Vasco (IT1045-16) | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | American Chemical Society | es_ES |
dc.relation | info:eu-repo/grantAgreement/MINECO/CTQ2016-74881-P | es_ES |
dc.rights | info:eu-repo/semantics/openAccess | es_ES |
dc.subject | palladium | es_ES |
dc.subject | C-H alkenylation | es_ES |
dc.subject | chromane | es_ES |
dc.title | Palladium(II)-catalyzed Intramolecular C-H Alkenylation for the Synthesis of Chromanes | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.rights.holder | © 2019, American Chemical Society | es_ES |
dc.relation.publisherversion | https://pubs.acs.org/doi/full/10.1021/acs.joc.8b03051 | es_ES |
dc.relation.publisherversion | https://doi.org/10.1021/acs.joc.8b03051 | es_ES |
dc.identifier.doi | 10.1021/acs.joc.8b03051 | |
dc.departamentoes | Química orgánica II | es_ES |
dc.departamentoeu | Kimika organikoa II | es_ES |