| dc.contributor.author | Prieto Aretxabaleta, Liher  | |
| dc.contributor.author | Sánchez Díez, Eduardo | |
| dc.contributor.author | Uria Pujana, Uxue | |
| dc.contributor.author | Reyes Martín, Efraim | |
| dc.contributor.author | Carrillo Fernández, María Luisa | |
| dc.contributor.author | Vicario Hernando, José Luis | |
| dc.date.accessioned | 2024-01-26T08:01:48Z | |
| dc.date.available | 2024-01-26T08:01:48Z | |
| dc.date.issued | 2017-04-10 | |
| dc.identifier.citation | Advanced Synthesis & Catalysisl 359(10) : 1678-1683 (2017) | es_ES |
| dc.identifier.issn | 1615-4169 | |
| dc.identifier.issn | 1615-4150 | |
| dc.identifier.uri | http://hdl.handle.net/10810/64341 | |
| dc.description.abstract | Formylcyclopropanes undergo activation
in the presence of an N-heterocyclic carbene catalyst
generating a donor-acceptor cyclopropane intermediate
with the ability to undergo ring-opening
followed by formal [4+2] cycloaddition with alkylideneoxindoles.
This enables the direct enantio- and
diastereoselective synthesis of tetrahydropyrano[
2,3-b]indoles through the use of a chiral NHC
catalyst.
Keywords: asymmetric | es_ES |
| dc.description.sponsorship | Spanish MINECO(FEDER-CTQ2014-52107), Basque Government (Grupos IT908-16), UPV/EHU (EHUA 16/10 and UFIQOSYC11/22) for financial support. L. P. and E. S.-D. | es_ES |
| dc.language.iso | eng | es_ES |
| dc.publisher | Wiley-VCH | es_ES |
| dc.relation | info:eu-repo/grantAgreement/MINECO/CTQ2014-52107 | es_ES |
| dc.rights | info:eu-repo/semantics/openAccess | es_ES |
| dc.subject | asymmetric catalysis | es_ES |
| dc.subject | cycloaddition; | es_ES |
| dc.subject | cyclopropanes | es_ES |
| dc.subject | N-heterocyclic carbenes | es_ES |
| dc.title | Catalytic Generation of Donor-Acceptor Cyclopropanes under N-Heterocyclic Carbene Activation and their Stereoselective Reaction with Alkylideneoxindoles | es_ES |
| dc.type | info:eu-repo/semantics/article | es_ES |
| dc.rights.holder | © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim | es_ES |
| dc.relation.publisherversion | https://doi.org/10.1002/adsc.201700198 | es_ES |
| dc.identifier.doi | 10.1002/adsc.201700198 | |
| dc.departamentoes | Química orgánica II | es_ES |
| dc.departamentoeu | Kimika organikoa II | es_ES |
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