dc.contributor.author | Arroyo-Córdoba, Ismael J. | |
dc.contributor.author | Sola Llano, Rebeca | |
dc.contributor.author | Epelde Elezcano, Nerea | |
dc.contributor.author | López Arbeloa, Iñigo María | |
dc.contributor.author | Martínez Martínez, Virginia ![ORCID](/themes/Mirage2//images/orcid_16x16.png) | |
dc.contributor.author | Peña Cabrera, Eduardo | |
dc.date.accessioned | 2024-02-08T09:54:50Z | |
dc.date.available | 2024-02-08T09:54:50Z | |
dc.date.issued | 2018-08-16 | |
dc.identifier.citation | The Journal of Organic Chemistry 83 : 10186-10196 (2018) | es_ES |
dc.identifier.issn | 0022-3263 | |
dc.identifier.issn | 1520-6904 | |
dc.identifier.uri | http://hdl.handle.net/10810/65164 | |
dc.description.abstract | The versatility in the synthesis of BODIPY derivatives in terms of
functionalization is further demonstrated. Particularly, in this work β−β’-BODIPY dimers
with varied functional groups in the meso-positions were synthetized in a very efficient
yields and short reaction times from a single platform. A photophysical study was carried in
all the compounds. The resultant dimers show absorption bands at around 600 nm as a
consequence of electronically coupled monomers disposed with a dihedral angle of around
30º, which is supported by theoretical simulations. The emission properties of these
molecules are distinguished by the appearance of an ICT state as the polarity of the solvent
increases. | es_ES |
dc.description.sponsorship | Financial support from Gobierno Vasco (IT912-16), Ministerio de Economía y Competitividad “MINECO” (MAT2017-83856-C3-3-P), and CONACyT (grants 253623, 123732) is acknowledged. I. J. A.-C. thanks CONACyT for graduate scholarship. Donation of 2,6-dimethyl-8-methylthioBODIPY by Cuantico de Mexico (www.cuantico.mx) is appreciated. | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | ACS | |
dc.rights | info:eu-repo/semantics/openAccess | es_ES |
dc.title | Fully Functionalizable β,β'-BODIPY Dimer: Synthesis, Structure, and Photophysical Signatures | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.rights.holder | © 2018 American Chemical Society | * |
dc.relation.publisherversion | https://pubs.acs.org/doi/10.1021/acs.joc.8b01429 | |
dc.identifier.doi | 10.1021/acs.joc.8b01429 | |
dc.departamentoes | Química física | es_ES |
dc.departamentoeu | Kimika fisikoa | es_ES |