dc.contributor.author | Prieto-Pascual, Unai | |
dc.contributor.author | Alli, Iñigo V. | |
dc.contributor.author | Bustos Rosas, Itxaso | |
dc.contributor.author | Vitorica Yrezabal, Iñigo J. | |
dc.contributor.author | Matxain Beraza, Jon Mattin | |
dc.contributor.author | Freixa Fernández, Zoraida | |
dc.contributor.author | Huertos Mansilla, Miguel Angel | |
dc.date | 2024-10-12 | |
dc.date.accessioned | 2024-02-08T09:56:24Z | |
dc.date.available | 2024-02-08T09:56:24Z | |
dc.date.issued | 2023-10-12 | |
dc.identifier.citation | Organometallics 42(20) : 2991-2998 (2023) | es_ES |
dc.identifier.issn | 0276-7333 | |
dc.identifier.issn | 1520-6041 | |
dc.identifier.uri | http://hdl.handle.net/10810/65174 | |
dc.description.abstract | Unsaturated 14-electron Rh(III) complexes are of great interest because of their involvement in stoichiometric and catalytic processes. Herein, we report the synthesis and characterization of one neutral and three cationic Rh(III) complexes bearing Si,N ligands, two of which are putative 14-electron cationic complexes. The reaction of the rhodium(I) precursor [RhCl(coe)2]2 with 8-(dimethylsilyl)quinoline (L1) resulted in the formation of the neutral rhodium(III) complex {Rh(Cl)(κ2-L1)2} (1-L1). From this compound, the cationic complex {Rh(κ2-L1)2(NCMe)}[BAr4F] (2-L1) can be synthesized by abstraction of the chlorine with Na[BAr4F]. The neutral complexes based on 8-(dimethylsilyl)-2-methylquinoline (L2) and 4-(dimethylsilyl)-9-phenylacridine (L3) could not be synthesized due to the bulky nature of the ligands. Therefore, the cationic compounds {Rh(κ2-L2)2}[BAr4F] (2-L2) and {Rh(κ2-L3)2}[BAr4F] (2-L3) were synthesized directly and proved to be very stable (solid and solution). Experimental (NMR and X-ray) and theoretical (NBO, QTAIM, and NCI) studies were performed and determined that the stability of the complexes is provided by weak agostic interactions. Furthermore, the cationic complexes were found to be active as catalysts in the hydrolysis of dihydrosilanes. | es_ES |
dc.description.sponsorship | This publication is part of the projects PID2019-111281GB-I00
funded by MCIN/AEI/10.13039/501100011033 and IT1741-22 and
IT1553-22 founded by Gobierno Vasco. The authors thank SGiker
for technical and human support. Universidad del Pais Vasco (to
U.P. PIF18/026) and IKERBASQUE (to M.H and Z.F.) are
acknowledge for personel funding. I. B. thank to Spanish Ministry
of Universities and European Union (Margarita Salas grant funded by the Next-GenerationEU, MARSA21/16). I. V-Y thanks Junta de
Andalucía (P21_00386) for funding | |
dc.language.iso | eng | es_ES |
dc.relation | info:eu-repo/grantAgreement/MICIN/PID2019-111281GB-I00 | |
dc.rights | info:eu-repo/semantics/embargoedAccess | es_ES |
dc.subject | catalysts | es_ES |
dc.subject | hydrolysis | |
dc.subject | ligands | |
dc.subject | metals | |
dc.subject | Silicon | |
dc.title | Air-Stable 14-Electron Rhodium(III) Complexes Bearing Si,N Ligands as Catalysts in Hydrolysis of Silanes | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.rights.holder | © 2023 American Chemical Society | * |
dc.relation.publisherversion | https://pubs.acs.org/doi/10.1021/acs.organomet.3c00324 | |
dc.identifier.doi | /10.1021/acs.organomet.3c00324 | |
dc.departamentoes | Química aplicada | es_ES |
dc.departamentoeu | Kimika aplikatua | es_ES |