dc.contributor.author | Arregi Joaristi, Aitor | |
dc.contributor.author | López Zabalbeitia, Gartzen ![ORCID](/themes/Mirage2//images/orcid_16x16.png) | |
dc.contributor.author | Amutio Izaguirre, Maider | |
dc.contributor.author | Artetxe Uria, Maite | |
dc.contributor.author | Barbarias Barainka, Itsaso | |
dc.contributor.author | Bilbao Elorriaga, Javier | |
dc.contributor.author | Olazar Aurrecoechea, Martin ![ORCID](/themes/Mirage2//images/orcid_16x16.png) | |
dc.date.accessioned | 2024-02-09T13:59:17Z | |
dc.date.available | 2024-02-09T13:59:17Z | |
dc.date.issued | 2017-12-09 | |
dc.identifier.citation | Fuel 216 : 233-244 (2018) | |
dc.identifier.issn | 0016-2361 | |
dc.identifier.uri | http://hdl.handle.net/10810/65935 | |
dc.description.abstract | The effect of reforming conditions (temperature, space time and steam/biomass ratio (S/B)) has been studied in the continuous biomass pyrolysis and in-line catalytic steam reforming process in order to establish suitable conditions for attenuating the deactivation of a commercial Ni catalyst by coke deposition. The experiments have been performed in a conical spouted bed and a fluidized bed reactor for the pyrolysis and reforming steps, respectively. Biomass fast pyrolysis was performed at 500 ºC and the reforming operating conditions studied are as follows: 550-700 ºC; space-time, 10-30 gcatalyst min gvolatiles-1, and; S/B ratio, 2-5. The coke deposited on the catalyst has been analyzed by temperature programmed oxidation (TPO), and two types of coke have been identified, i.e., the coke deposited on the Ni active sites and the one separated from these sites, without filamentous coke being observed by transmission electron microscopy (TEM). Coke deposition has been related to the decomposition of the oxygenates derived from biomass pyrolysis and the re-polymerization of phenolic oxygenates. Suitable conditions to achieve almost full conversion with a H2 yield of up to 95 % and stability for 160 min on stream, the following have been established: 600 ºC, space time of 30 gcatalyst min gvolatiles-1 and S/B ratio of 3. | es_ES |
dc.description.sponsorship | This work was carried out with financial support from the Ministry of Economy and Competitiveness of the Spanish Government (CTQ2016-75535-R (AEI/FEDER, UE) and CTQ-2015-69436-R (MINECO/FEDER, UE)), the Basque Government (IT748-13) and the University of the Basque Country (UFI 11/39). I. Barbarias thanks the University of the Basque Country for her postgraduate grant (UPV/EHU 2016). | |
dc.language.iso | eng | es_ES |
dc.publisher | Elsevier | |
dc.relation | info:eu-repo/grantAgreement/MINECO/CTQ2016-75535-R | |
dc.relation | info:eu-repo/grantAgreement/MINECO/CTQ-2015-69436-R | |
dc.rights | info:eu-repo/semantics/openAccess | es_ES |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/es/ | |
dc.subject | biomass | es_ES |
dc.subject | pyrolysis | es_ES |
dc.subject | reforming | es_ES |
dc.subject | hydrogen | es_ES |
dc.subject | deactivation | es_ES |
dc.subject | bio-oil | es_ES |
dc.title | Role of operating conditions in the catalyst deactivation in the in-line steam reforming of volatiles from biomass fast pyrolysis | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.rights.holder | © 2017. This manuscript version is made available under the CC-BY-NC-ND 4.0 license https://creativecommons.org/licenses/by-nc-nd/4.0/ | |
dc.relation.publisherversion | https://www.sciencedirect.com/science/article/abs/pii/S0016236117315697 | es_ES |
dc.identifier.doi | 10.1016/j.fuel.2017.12.002 | |
dc.departamentoes | Ingeniería química | |
dc.departamentoeu | Ingeniaritza kimikoa | |