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5-Methoxymethyl furfural production by acid heterogeneous catalytic etherification of 5-hydroxymethyl furfural

dc.contributor.authorDíaz Maizkurrena, Paula
dc.contributor.authorRequies Martínez, Jesús María ORCID
dc.contributor.authorIriondo Hernández, Aitziber ORCID
dc.contributor.authorArias Ergueta, Pedro Luis
dc.contributor.authorMariscal, R.
dc.date.accessioned2024-04-19T18:17:54Z
dc.date.available2024-04-19T18:17:54Z
dc.date.issued2024-01
dc.identifier.citationCatalysis Today 426 : (2024) // Article ID 114374es_ES
dc.identifier.issn0920-5861
dc.identifier.issn1873-4308
dc.identifier.urihttp://hdl.handle.net/10810/66824
dc.description.abstractThe use of non-edible raw materials from agriculture as a form of biomass to obtain carbon-based compounds is the most viable solution to replace fossil resources. Within this, 5-hydroxymethyl furfural (HMF) is a platform monomer from which other high value-added monomers are obtained, such as 2,5-furandicarboxylic acid (FDCA), a compound that can be obtained from 5-methoxymethyl furfural (MMF), and which can be used as a fuel, fuel additive or polymer precursor. Several catalysts (mostly zeolites) have been tested to produce MMF. Specifically, with a ZSM-5 zeolite a yield towards this compound of 97 % has been achieved, carrying out the reaction in a batch reactor for 5 h. Through the characterization of the catalysts, a strong correlation has been observed between the acidity of these catalysts and their effectiveness in the reaction of HMF through MMF.es_ES
dc.description.sponsorshipThis research was supported by the University of the Basque Country (UPV/EHU), Basque Government (IT1554-22), and the Spanish Ministry of Economy, Industry and Competitiveness (PID2021-122736OB-C43 and PID2021-122736OB-C41). The authors express their gratitude to Roberto Palos and Iratxe Crespo from the Chemical Engineering department of the UPV/EHU for their help and assistance, for letting us use their FTIR equipment. The authors also express their gratitude to Pedro J. Maireles from the Inorganic Chemistry, Crystallography and Mineralogy department of the University of Málaga (UMA) for performing all XPS analyses.es_ES
dc.language.isoenges_ES
dc.publisherElsevieres_ES
dc.relationinfo:eu-repo/grantAgreement/MICINN/PID2021-122736OB-C43es_ES
dc.relationinfo:eu-repo/grantAgreement/MICINN/PID2021-122736OB-C41es_ES
dc.rightsinfo:eu-repo/semantics/openAccesses_ES
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/es/*
dc.subjectHMFes_ES
dc.subjectMMFes_ES
dc.subjectzeoliteses_ES
dc.subjectnon-noble metalses_ES
dc.subjectBrønsted acid siteses_ES
dc.subjectLewis acid siteses_ES
dc.title5-Methoxymethyl furfural production by acid heterogeneous catalytic etherification of 5-hydroxymethyl furfurales_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.rights.holder© 2023 The Authors. Published by Elsevier B.V. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/)es_ES
dc.rights.holderAtribución 3.0 España*
dc.relation.publisherversionhttps://www.sciencedirect.com/science/article/pii/S092058612300398Xes_ES
dc.identifier.doi10.1016/j.cattod.2023.114374
dc.departamentoesIngeniería química y del medio ambientees_ES
dc.departamentoeuIngeniaritza kimikoa eta ingurumenaren ingeniaritzaes_ES


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© 2023 The Authors. Published by Elsevier B.V. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/)
Except where otherwise noted, this item's license is described as © 2023 The Authors. Published by Elsevier B.V. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/)