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dc.contributor.authorBarquero Salaberria, Aitor
dc.contributor.authorLlorente Zabala, Oihane
dc.contributor.authorMinudri, Daniela
dc.contributor.authorPaulis Lumbreras, María
dc.contributor.authorLeiza Recondo, José Ramón
dc.date.accessioned2024-04-29T17:59:25Z
dc.date.available2024-04-29T17:59:25Z
dc.date.issued2023-08
dc.identifier.citationMacromolecular Reaction Engineering 17(4) : (2023) // Article ID 2300015es_ES
dc.identifier.issn1862-8338
dc.identifier.issn1862-832X
dc.identifier.urihttp://hdl.handle.net/10810/66931
dc.description.abstractIn this work, solvent-free waterborne polyurethane-poly(meth)acrylate hybrid dispersions that can be used to formulate anticorrosive paints are synthesized. To achieve the anticorrosive protection, a phosphate containing polymerizable surfactant, Sipomer PAM 200 is incorporated to the hybrids. The presence of phosphate groups can produce an iron phosphate passivation layer to provide coatings with anticorrosive properties. These properties are tested in both mild and harsh corrosive environments. It is observed that when the films are dried at 60% relative humidity conditions, very poor anticorrosive protection is achieved because no phosphatization is obtained, but increasing the humidity to 85% during the drying step allows the formation of the passivation layer providing good anticorrosive properties.es_ES
dc.description.sponsorshipFinancial support from Eusko Jaurlaritza (No. GV-IT1525-22) and MINECO (No. PID2021-123146OB-I00) is gratefully acknowledged. Project PDC202-1-12141-6-100 was founded by MCIN/AEI/10.13039/5011000110033 and by the European Union Next Generation EU/PRTR.es_ES
dc.language.isoenges_ES
dc.publisherWileyes_ES
dc.relationinfo:eu-repo/grantAgreement/MICINN/PID2021-123146OB-I00es_ES
dc.rightsinfo:eu-repo/semantics/openAccesses_ES
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/es/*
dc.subjectcorrosiones_ES
dc.subjectphosphatization waterborne dispersiones_ES
dc.subjectpolyurethane-poly(meth)acrylatees_ES
dc.titleSynthesis of Waterborne Anticorrosive Coatings Based on The Incorporation of Phosphate Groups to Polyurethane-Acrylate Hybridses_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.rights.holder© 2023 The Authors. Macromolecular Reaction Engineering published by Wiley-VCH GmbH. This is an open access article under the terms of the Creative Commons Attribution-NonCommercial-NoDerivs License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non-commercial and no modifications or adaptations are made.es_ES
dc.rights.holderAtribución-NoComercial-SinDerivadas 3.0 España*
dc.relation.publisherversionhttps://onlinelibrary.wiley.com/doi/full/10.1002/mren.202300015es_ES
dc.identifier.doi10.1002/mren.202300015
dc.departamentoesQuímica aplicadaes_ES
dc.departamentoeuKimika aplikatuaes_ES


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© 2023 The Authors. Macromolecular Reaction Engineering published by Wiley-VCH GmbH.
This is an open access article under the terms of the Creative Commons Attribution-NonCommercial-NoDerivs License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non-commercial and no modifications or adaptations are made.
Except where otherwise noted, this item's license is described as © 2023 The Authors. Macromolecular Reaction Engineering published by Wiley-VCH GmbH. This is an open access article under the terms of the Creative Commons Attribution-NonCommercial-NoDerivs License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non-commercial and no modifications or adaptations are made.