dc.contributor.author | Torres Olea, Benjamín | |
dc.contributor.author | Pérez Merchán, Antonio Manuel | |
dc.contributor.author | Díaz Maizkurrena, Paula | |
dc.contributor.author | Requies Martínez, Jesús María | |
dc.contributor.author | Moreno Tost, Ramón | |
dc.contributor.author | Cecilia, Juan Antonio | |
dc.contributor.author | García Sancho, Cristina | |
dc.contributor.author | Maireles Torres, Pedro Jesús | |
dc.date.accessioned | 2024-05-02T18:00:56Z | |
dc.date.available | 2024-05-02T18:00:56Z | |
dc.date.issued | 2024-02 | |
dc.identifier.citation | Catalysis Today 427 : (2024) // Article ID 114439 | es_ES |
dc.identifier.issn | 0920-5861 | |
dc.identifier.issn | 1873-4308 | |
dc.identifier.uri | http://hdl.handle.net/10810/67316 | |
dc.description.abstract | The use of zeolites as catalysts in the transformation of glucose and 5-hydroxymethylfurfural (HMF) into 5-ethoxymethylfurfural (EMF) was evaluated. The behaviour of the catalysts could be explained by their morphology, composition, acid properties and chemical coordination of the active sites. The progress of the reaction was followed by High Performance Liquid Chromatography (HPLC) and 13C Nuclear Magnetic Resonance (NMR). Several intermediates were identified, and a reaction path is proposed. Different cosolvents were also employed in this study to enhance the selectivity towards different possible valuable compounds, and they were found to have a positive influence for the production of EMF and furfural. | es_ES |
dc.description.sponsorship | Funding: This research was funded by Spanish Ministry of Science and Innovation (PID2021–122736OB-C42 and PID2021–122736OB-C43), FEDER (European Union) funds (PID2021–122736OB-C42, P20–00375, UMA20-FEDERJA-088) and B. Torres-Olea thanks Ministerio de Universidades for his predoctoral contract (FPU20/02334). Moreover, authors want to thank the funding for open access charge to Universidad de Málaga / CBUA. | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | Elsevier | es_ES |
dc.relation | info:eu-repo/grantAgreement/MICINN/PID2021–122736OB-C42 | es_ES |
dc.relation | info:eu-repo/grantAgreement/MICINN/PID2021–122736OB-C43 | es_ES |
dc.rights | info:eu-repo/semantics/openAccess | es_ES |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/es/ | * |
dc.subject | 5-hydroxymethylfurfural | es_ES |
dc.subject | 5-ethoxymethylfurfural | es_ES |
dc.subject | glucose | es_ES |
dc.subject | dehydration | es_ES |
dc.subject | etherification | es_ES |
dc.subject | zeolite | es_ES |
dc.title | Application of zeolites for the production of biofuels and furans from hexose sugars in ethanol | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.rights.holder | © 2023 The Authors. Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-
nc-nd/4.0/). | es_ES |
dc.rights.holder | Atribución-NoComercial-SinDerivadas 3.0 España | * |
dc.relation.publisherversion | https://www.sciencedirect.com/science/article/pii/S0920586123004637 | es_ES |
dc.identifier.doi | 10.1016/j.cattod.2023.114439 | |
dc.departamentoes | Ingeniería química y del medio ambiente | es_ES |
dc.departamentoeu | Ingeniaritza kimikoa eta ingurumenaren ingeniaritza | es_ES |