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Influence of Thermally-Induced Structural Transformations over Magnetic and Luminiscence Properties of Tartrate-based Chiral Lanthanide Organic-Frameworks
(RSC, 2020-05-04)
This work reports on the synthesis and characterization of five enantiomeric pairs of isostructural 3D metal-organic
frameworks (MOFs) with the general formula {[Ln2(μ4-tar)2(μ-tar)(H2O)2]·xH2O}n [where Ln(III) = Tb (Tb-L ...
Magneto-thermal properties and slow magnetic relaxation in Mn(II)Ln(III) complexes: Influence of magnetic coupling on the magneto-caloric effect
(2022-08-05)
A family of Mn(II)Ln(III) dinuclear and tetranuclear complexes (Ln = Gd and Dy) has been prepared from the
compartmental ligands N,N’-dimethyl-N,N’-bis(2-hydroxy-3-formyl-5-bromobenzyl)ethylenediamine
(H2L1
) and ...
Spin canting and slow magnetic relaxation in mononuclear cobalt(ii) sulfadiazine ternary complexes
(RSC, 2024-01)
Monomeric [Co(SDZ)2phen] (1) and [Co(SDZ)(bq)Cl] (2) complexes (SDZ = sulfadiazine, phen = 1,10-phenanthroline, and bq = 2,2′-biquinoline) have been synthesized and characterized. X-ray diffraction studies indicate that ...