Heterogeneous catalytic activity on Mn, Fe and Co-based metalloporphyrinic Solid Coordination Frameworks (SCFs)

Abstract

Solid Coordination Frameworks (SCFs) have been widely explored on different catalytic reactions, and during the past years metalloporphyrins have been investigating in order to mimick it in the solid state their natural activity. Herein we present the catalytic activity results towards the oxidation reactions of different alcohols for MnTPPS, FeTCPP and CoTPPS based metalloporphyrinc SCFs (TPPS= meso-tetrasulfonatophenylporphyrin, TCPP= meso-tetracarboxyphenylporphyrin). Additionally, Knoevenagel condensations and a one-pot reaction involving the FeTCPP based SCF catalysts have been carried out.