Twisted Aromatic Frameworks: Readily Exfoliable and Solution-Processable Two-Dimensional Conjugated Microporous Polymers

Marco, A. Belen; Cortizo Lacalle, Diego; Pérez Miqueo, Iñigo; Valenti, Giovanni; Boni, Alessandro; Plas, Jan; Strutynski, Karol; De Feyter, Steven; Paolucci, Francesco; Montes Ramírez, Mario; Khlobystov, Andrei N.; Melle Franco, Manuel; Mateo Alonso, Aurelio

dc.contributor.author	Marco, A. Belen
dc.contributor.author	Cortizo Lacalle, Diego
dc.contributor.author	Pérez Miqueo, Iñigo
dc.contributor.author	Valenti, Giovanni
dc.contributor.author	Boni, Alessandro
dc.contributor.author	Plas, Jan
dc.contributor.author	Strutynski, Karol
dc.contributor.author	De Feyter, Steven
dc.contributor.author	Paolucci, Francesco
dc.contributor.author	Montes Ramírez, Mario
dc.contributor.author	Khlobystov, Andrei N.
dc.contributor.author	Melle Franco, Manuel
dc.contributor.author	Mateo Alonso, Aurelio
dc.date.accessioned	2018-06-22T12:35:29Z
dc.date.available	2018-06-22T12:35:29Z
dc.date.issued	2017
dc.identifier.citation	Angewandte Chemie-International Edition 56(24) : 6946-6951 (2017)	es_ES
dc.identifier.issn	1521-3773
dc.identifier.uri	http://hdl.handle.net/10810/27674
dc.description.abstract	Twisted two-dimensional aromatic frameworks have been prepared by overcrowding the nodes with bulky and rigid substituents. The highly distorted aromatic framework with alternating out-of-plane substituents results in diminished interlayer interactions that favor the exfoliation and dispersion of individual layers in organic media.	es_ES
dc.description.sponsorship	We are grateful to the Basque Science Foundation for Science (Ikerbasque), POLYMAT, the University of the Basque Country (SGIker), the Deutsche Forschungsgemeinschaft (AU 373/3-1 and MA 5215/4-1), Gobierno de Espana/FEDER (Ministerio de Economia y Competitividad, CTQ2015-71936-REDT, CTQ2016-77970-R, and ENE2015-66975-C3), Gobierno Vasco (BERC program, PC2015-1-01(06-37), and IT1069-16), Diputacion Foral de Guipuzkoa (2015-CIEN-000054-01), CICECO-Aveiro Institute of Materials, POCI-01-0145-FEDER-007679 (FCT ref. UID/CTM/50011/ 2013), ON2 (NORTE-07-0162-FEDER-000086), the Fund of Scientific Research-Flanders (FWO), the Internal Funds KU Leuven, the Belgian Federal Science Policy Office (IAP-7/05), and the Nanoscale and Microscale Research Centre (NMRC, University of Nottingham, UK) for access to TEM. We have received funding for the research leading to these results from the European Union Seventh Framework Programme as a European Research Area Action (ERA-Chemistry) and a Marie Curie Action (Career Integration Grant No. 618247) and from the European Union Framework Programme for Research and Innovation Horizon 2020 as a Future and Emerging Technologies Action (FET Open) under Grant Agreement No. 664878 (2D-INK).	es_ES
dc.language.iso	eng	es_ES
dc.publisher	Wiley VCH	es_ES
dc.relation	info:eu-repo/grantAgreement/EC/FP7/618247	es_ES
dc.relation	info:eu-repo/grantAgreement/MINECO/CTQ2015-71936-REDT
dc.relation	info:eu-repo/grantAgreement/MINECO/CTQ2016-77970-R
dc.relation	info:eu-repo/grantAgreement/MINECO/ENE2015-66975-C3
dc.rights	info:eu-repo/semantics/openAccess	es_ES
dc.rights.uri	http://creativecommons.org/licenses/by-nc/3.0/es/	*
dc.subject	carbon nanostructures	es_ES
dc.subject	materials science	es_ES
dc.subject	nanocarbons	es_ES
dc.subject	organic frameworks	es_ES
dc.subject	twisted aromatic systems	es_ES
dc.subject	covalent organic frameworks	es_ES
dc.subject	metal-free electrocatalysts	es_ES
dc.subject	oxygen reduction	es_ES
dc.subject	hydrogen evolution	es_ES
dc.subject	graphene	es_ES
dc.subject	carbon	es_ES
dc.subject	nanosheets	es_ES
dc.subject	chemistry	es_ES
dc.subject	functionalization	es_ES
dc.subject	delamination	es_ES
dc.title	Twisted Aromatic Frameworks: Readily Exfoliable and Solution-Processable Two-Dimensional Conjugated Microporous Polymers	es_ES
dc.type	info:eu-repo/semantics/article	es_ES
dc.rights.holder	This is an open access article under the terms of the Creative Commons Attribution‐NonCommercial License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes.	es_ES
dc.rights.holder	Atribución-NoComercial 3.0 España	*
dc.relation.publisherversion	https://onlinelibrary.wiley.com/doi/full/10.1002/anie.201700271	es_ES
dc.identifier.doi	10.1002/anie.201700271
dc.identifier.doi	10.1002/anie.201700271
dc.departamentoes	Química aplicada	es_ES
dc.departamentoeu	Kimika aplikatua	es_ES

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This is an open access article under the terms of the Creative Commons Attribution‐NonCommercial License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes.

Except where otherwise noted, this item's license is described as This is an open access article under the terms of the Creative Commons Attribution‐NonCommercial License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes.