2D and 3D Immobilization of Carbon Nanomaterials into PEDOT via Electropolymerization of a Functional Bis-EDOT Monomer
dc.contributor.author | Domínguez Alfaro, Antonio | |
dc.contributor.author | Gómez, I. Jénnifer | |
dc.contributor.author | Alegret Ramón, Nuria | |
dc.contributor.author | Mecerreyes Molero, David | |
dc.contributor.author | Prato, Maurizio | |
dc.date.accessioned | 2021-02-05T19:05:56Z | |
dc.date.available | 2021-02-05T19:05:56Z | |
dc.date.issued | 2021-01-29 | |
dc.identifier.citation | Polymers 13 (3) : (2021) // Article ID 436 | es_ES |
dc.identifier.issn | 2073-4360 | |
dc.identifier.uri | http://hdl.handle.net/10810/50071 | |
dc.description.abstract | Carbon nanomaterials (CNMs) and conjugated polymers (CPs) are actively investigated in applications such as optics, catalysis, solar cells, and tissue engineering. Generally, CNMs are implemented in devices where the relationship between the active elements and the micro and nanostructure has a crucial role. However, they present some limitations related to solubility, processibility and release or degradability that affect their manufacturing. CPs, such as poly(3,4-ethylenedioxythiophene) (PEDOT) or derivatives can hide this limitation by electrodeposition onto an electrode. In this work we have explored two different CNMs immobilization methods in 2D and 3D structures. First, CNM/CP hybrid 2D films with enhanced electrochemical properties have been developed using bis-malonyl PEDOT and fullerene C<sub>60</sub>. The resulting 2D films nanoparticulate present novel electrochromic properties. Secondly, 3D porous self-standing scaffolds were prepared, containing carbon nanotubes and PEDOT by using the same bis-EDOT co-monomer, which show porosity and topography dependence on the composition. This article shows the validity of electropolymerization to obtain 2D and 3D materials including different carbon nanomaterials and conductive polymers. | es_ES |
dc.description.sponsorship | This research was funded by the Spanish Ministry of Economy and Competitiveness MINECO (project CTQ2016-76721-R), the University of Trieste, Diputación Foral de Gipuzkoa program Red (101/16), the European Commission (H2020-MSCA-RISE-2016, grant agreement no. 734381, acronym CARBO-IMmap) and ELKARTEK bmG2017 (ref: Elkartek KK-2017/00008, BOPV resolution: 8 Feb 2018). M.P., as the recipient of the AXA Chair, is grateful to the AXA Research Fund for financial support. This work was performed under the Maria de Maeztu Units of Excellence Program from the Spanish State Research Agency Grant no. MDM-2017-0720. N.A. has received funding from the European Union’s Horizon 2020 research and innovation programme under the Marie Sklodowska-Curie grant agreement no. 753293, acronym NanoBEAT. | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | MDPI | es_ES |
dc.relation | info:eu-repo/grantAgreement/EC/H2020/734381 | es_ES |
dc.relation | info:eu-repo/grantAgreement/EC/H2020/753293 | es_ES |
dc.relation | info:eu-repo/grantAgreement/MINECO/CTQ2016-76721-R | es_ES |
dc.rights | info:eu-repo/semantics/openAccess | es_ES |
dc.rights.uri | http://creativecommons.org/licenses/by/4.0/ | |
dc.subject | CNT | es_ES |
dc.subject | PEDOT | es_ES |
dc.subject | electropolymerization | es_ES |
dc.subject | functional EDOT monomers | es_ES |
dc.title | 2D and 3D Immobilization of Carbon Nanomaterials into PEDOT via Electropolymerization of a Functional Bis-EDOT Monomer | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.date.updated | 2021-02-05T14:13:12Z | |
dc.rights.holder | © 2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). | es_ES |
dc.relation.publisherversion | https://www.mdpi.com/2073-4360/13/3/436 | es_ES |
dc.identifier.doi | 10.3390/polym13030436 | |
dc.contributor.funder | European Commission | |
dc.departamentoes | Ciencia y tecnología de polímeros | |
dc.departamentoeu | Polimeroen zientzia eta teknologia |
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Except where otherwise noted, this item's license is described as © 2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).