dc.contributor.author | Peñas Núñez, Mario Iván | |
dc.contributor.author | Ocando, Connie | |
dc.contributor.author | Penott Chang, Evis | |
dc.contributor.author | Safari, Maryam | |
dc.contributor.author | Ezquerra, Tiberio A. | |
dc.contributor.author | Rebollar, Esther ![ORCID](/themes/Mirage2//images/orcid_16x16.png) | |
dc.contributor.author | Nogales, Aurora | |
dc.contributor.author | Hernández, Rebeca | |
dc.contributor.author | Müller Sánchez, Alejandro Jesús ![ORCID](/themes/Mirage2//images/orcid_16x16.png) | |
dc.date.accessioned | 2021-07-19T11:23:36Z | |
dc.date.available | 2021-07-19T11:23:36Z | |
dc.date.issued | 2021-06-04 | |
dc.identifier.citation | Polymer 226 : (2021) // Article ID 123812 | es_ES |
dc.identifier.issn | 0032-3861 | |
dc.identifier.issn | 1873-2291 | |
dc.identifier.uri | http://hdl.handle.net/10810/52516 | |
dc.description.abstract | In this work, we prepare and characterize multiphasic thin films containing poly(epsilon-caprolactone), PCL, poly (butylene succinate), PBS, and a poly (butylene succinate-ran-epsilon-caprolactone) (PBS-ran-PCL) random copolyester. To that aim, thin films were prepared by sequential dipping of a silicon substrate into chloroform solutions of the respective polymers. The preparation method resulted in films with varying compositions of PCL and PBS components depending on the initial concentration of the dipping solutions and the number of dipping steps employed for the preparation of the samples. Atomic force microscopy (AFM), grazing incidence X-ray scattering at wide angle (GIWAXS) and scattering-type scanning near-field optical microscopy (s-SNOM) and Fourier transform infrared nanospectroscopy (nano-FTIR) were employed to characterize the films obtained. As chloroform can dissolve all components, the final composition of the film was always rich in the last deposited layer component. The thin films obtained were semicrystalline with a complex axialitic or dendritic morphology of the dominant component (that one deposited last) with traces of the other components, whose presence and location was revealed by s-SNOM/nano-FTIR. | es_ES |
dc.description.sponsorship | This study was supported by Spanish Ministry of Science, Innovation and Universities (MAT2017-83014-C2-1-P, MAT2017-83014-C2-2-P, PID2019-107514 GB-I00/AEI/10.13039/501100011033 and PID2019-106125 GB-I00/AEI/10.13039/501100011033). We also acknowledge funding by Basque Government through grant IT1309-19. The authors acknowledge beamtime access at ALBA BL11 via proposal 2018072905 and the assistance of JC Martinez during the measurements. We would also like to thank the financial support provided by the BIODEST project; this project has received funding from the European Union's Horizon 2020 research and innovation programme under the Marie Skłodowska-Curie grant agreement No. 778092. CO wants to acknowledge “Diputación Foral de Gipuzkoa” in the framework program “Fellows Gipuzkoa de Atracción y Retención de Talento” | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | Elsevier | es_ES |
dc.relation | info:eu-repo/grantAgreement/MICINN/MAT2017-83014-C2-1-P | es_ES |
dc.relation | info:eu-repo/grantAgreement/MICINN/MAT2017-83014-C2-2-P | es_ES |
dc.relation | info:eu-repo/grantAgreement/MICINN/PID2019-107514 GB-I00 | es_ES |
dc.relation | info:eu-repo/grantAgreement/MICINN/PID2019-106125 GB-I00 | es_ES |
dc.relation | info:eu-repo/grantAgreement/EC/H2020/778092 | es_ES |
dc.rights | info:eu-repo/semantics/openAccess | es_ES |
dc.rights.uri | http://creativecommons.org/licenses/by/3.0/es/ | * |
dc.subject | poly(ε-caprolactone) | es_ES |
dc.subject | poly(butylene succinate) | es_ES |
dc.subject | Random copolyesters | es_ES |
dc.subject | thin-films | es_ES |
dc.subject | layer-by-layer dip-coating | es_ES |
dc.subject | s-SNOM | es_ES |
dc.subject | nano-FTIR | es_ES |
dc.title | Nanostructural Organization of Thin Films Prepared by Sequential Dip-Coating Deposition of Poly(Butylene Succinate), Poly(ε-Caprolactone) and Their Copolyesters (PBS-ran-PCL) | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.rights.holder | This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY 4.0) | es_ES |
dc.rights.holder | Atribución 3.0 España | * |
dc.relation.publisherversion | https://www-sciencedirect-com.ehu.idm.oclc.org/science/article/pii/S0032386121004353?via%3Dihub#abs0010 | es_ES |
dc.identifier.doi | 10.1016/j.polymer.2021.123812 | |
dc.contributor.funder | European Commission | |
dc.departamentoes | Polímeros y Materiales Avanzados: Física, Química y Tecnología | es_ES |
dc.departamentoeu | Polimero eta Material Aurreratuak: Fisika, Kimika eta Teknologia | es_ES |