Access to 2,6-Dipropargylated BODIPYs as "Clickable" Congeners of Pyrromethene-567 Dye: Photostability and Synthetic Versatility

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Date
2021-09-03
Author
Uriel, Clara
Gómez López, Ana María
García Martínez de la Hidalga, Enrique
Bañuelos Prieto, Jorge ORCID
García Moreno, Inmaculada
López Pérez, José Cristóbal
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  Estadisticas en RECOLECTA
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Organic Letters 23(17) : 6801-6806 (2021)
URI
http://hdl.handle.net/10810/53343
Abstract
Hitherto unreported 2,6-dipropargyl-1,3,5,7-tetramethyl BODIPYs can be efficiently prepared by a Nicholas reaction/decomplexation protocol from 1,3,5,7-tetramethyl BODIPYs. The title compounds, which improve the BODIPY photostability by retaining their inherent photophysical and photochemical properties, can be engaged in efficient copper(I)-catalyzed azide-alkyne cycloaddition (CuAAC) "click-type" reactions with azido derivatives to provide all-BODIPY-triads or conjugated BODIPYs.
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Except where otherwise noted, this item's license is described as This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY 4.0)