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Access to 2,6-Dipropargylated BODIPYs as "Clickable" Congeners of Pyrromethene-567 Dye: Photostability and Synthetic Versatility

dc.contributor.authorUriel, Clara
dc.contributor.authorGómez López, Ana María
dc.contributor.authorGarcía Martínez de la Hidalga, Enrique
dc.contributor.authorBañuelos Prieto, Jorge ORCID
dc.contributor.authorGarcía Moreno, Inmaculada
dc.contributor.authorLópez Pérez, José Cristóbal
dc.date.accessioned2021-10-11T09:30:27Z
dc.date.available2021-10-11T09:30:27Z
dc.date.issued2021-09-03
dc.identifier.citationOrganic Letters 23(17) : 6801-6806 (2021)es_ES
dc.identifier.issn1523-7060
dc.identifier.issn1523-7052
dc.identifier.urihttp://hdl.handle.net/10810/53343
dc.description.abstractHitherto unreported 2,6-dipropargyl-1,3,5,7-tetramethyl BODIPYs can be efficiently prepared by a Nicholas reaction/decomplexation protocol from 1,3,5,7-tetramethyl BODIPYs. The title compounds, which improve the BODIPY photostability by retaining their inherent photophysical and photochemical properties, can be engaged in efficient copper(I)-catalyzed azide-alkyne cycloaddition (CuAAC) "click-type" reactions with azido derivatives to provide all-BODIPY-triads or conjugated BODIPYs.es_ES
dc.description.sponsorshipWe gratefully acknowledge the Spanish Ministerio de Ciencia e Innovacion for financial support (Project Nos. RTI2018094862-B-100, MAT2017-83856-C3-1-P and 3-P; PiD2020114755GB-C31 and -C33) and the Gobierno Vasco (GV) (Project No. IT912-16) for financial support. We are indebted to Ms. Marina Rodriguez (IQOG-CSIC) for skillful technical support.es_ES
dc.language.isoenges_ES
dc.publisherAmerican Chemical Societyes_ES
dc.relationinfo:eu-repo/grantAgreement/MICINN/RTI2018-094862-B-100es_ES
dc.relationinfo:eu-repo/grantAgreement/MICINN/MAT2017-83856-C3-1-Pes_ES
dc.relationinfo:eu-repo/grantAgreement/MICINN/MAT2017-83856-C3-3-Pes_ES
dc.relationinfo:eu-repo/grantAgreement/MICINN/PiD2020-114755GB-C31es_ES
dc.relationinfo:eu-repo/grantAgreement/MICINN/PiD2020-114755GB-C33es_ES
dc.rightsinfo:eu-repo/semantics/openAccesses_ES
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/es/*
dc.subjectderivativeses_ES
dc.subjectchemistryes_ES
dc.subjectprobeses_ES
dc.titleAccess to 2,6-Dipropargylated BODIPYs as "Clickable" Congeners of Pyrromethene-567 Dye: Photostability and Synthetic Versatilityes_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.rights.holderThis is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY 4.0)es_ES
dc.rights.holderAtribución 3.0 España*
dc.relation.publisherversionhttps://pubs-acs-org.ehu.idm.oclc.org/doi/10.1021/acs.orglett.1c02380es_ES
dc.identifier.doi10.1021/acs.orglett.1c02380
dc.departamentoesQuímica físicaes_ES
dc.departamentoeuKimika fisikoaes_ES


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This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY 4.0)
Except where otherwise noted, this item's license is described as This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY 4.0)