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dc.contributor.authorKolesniková, Lucie
dc.contributor.authorLeón Ona, Iker
dc.contributor.authorAlonso Alonso, Elena Rita
dc.contributor.authorMata, Santiago
dc.contributor.authorAlonso, Jose Luis
dc.date.accessioned2021-11-12T09:28:42Z
dc.date.available2021-11-12T09:28:42Z
dc.date.issued2021-11-08
dc.identifier.citationAngewandte Chemie-International Edition 60(46) : 24461-24466 (2021)es_ES
dc.identifier.issn1433-7851
dc.identifier.issn1521-3773
dc.identifier.urihttp://hdl.handle.net/10810/53740
dc.description.abstract[EN]The large amount of unstable species in the realm of interstellar chemistry drives an urgent need to develop efficient methods for the in situ generations of molecules that enable their spectroscopic characterizations. Such laboratory experiments are fundamental to decode the molecular universe by matching the interstellar and terrestrial spectra. We propose an approach based on laser ablation of nonvolatile solid organic precursors. The generated chemical species are cooled in a supersonic expansion and probed by high-resolution microwave spectroscopy. We present a proof of concept through a simultaneous formation of interstellar compounds and the first generation of aminocyanoacetylene using diaminomaleonitrile as a prototypical precursor. With this micro-laboratory, we open the door to generation of unsuspected species using precursors not typically accessible to traditional techniques such as electric discharge and pyrolysis.es_ES
dc.description.sponsorshipThis work was supported by funding from the Czech Science Foundation (GACR, grant 19-25116Y), Ministerio de Ciencia e Innovacion (grants PID2019-111396GB-I00, CTQ2016-76393-P), Junta de Castilla y Leon (grants VA244P20, VA077U16), and European Research Council under the European Union's Seventh Framework Programme ERC-2013-SyG, Grant Agreement n. 610256 NANOCOSMOS. E.R.A. thanks Fundacion Biofisica Bizkaia (FBB) for a postdoctoral contract.es_ES
dc.language.isoenges_ES
dc.publisherWileyes_ES
dc.relationinfo:eu-repo/grantAgreement/EC/H2020/610256es_ES
dc.relationinfo:eu-repo/grantAgreement/MICINN/PID2019-111396GB-I00es_ES
dc.relationinfo:eu-repo/grantAgreement/MICINN/CTQ2016-76393-Pes_ES
dc.rightsinfo:eu-repo/semantics/openAccesses_ES
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/es/*
dc.subjectchemical synthesises_ES
dc.subjectinterstellar mediumes_ES
dc.subjectlaser ablationes_ES
dc.subjectmolecular generationes_ES
dc.subjectrotational spectroscopyes_ES
dc.titleAn Innovative Approach for the Generation of Species of the Interstellar Mediumes_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.rights.holder2021 The Authors. Published under a Creative Commons license Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0).es_ES
dc.rights.holderAtribución-NoComercial-SinDerivadas 3.0 España*
dc.relation.publisherversionhttps://onlinelibrary.wiley.com/doi/10.1002/anie.202110325es_ES
dc.identifier.doi10.1002/anie.202110325
dc.contributor.funderEuropean Commission
dc.departamentoesQuímica físicaes_ES
dc.departamentoeuKimika fisikoaes_ES


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2021 The Authors. Published under a Creative Commons license Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0).
Except where otherwise noted, this item's license is described as 2021 The Authors. Published under a Creative Commons license Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0).