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dc.contributor.authorMato Santamaría, Raquel
dc.contributor.authorManzano, Rubén ORCID
dc.contributor.authorReyes Martín, Efraim
dc.contributor.authorPrieto Aretxabaleta, Liher ORCID
dc.contributor.authorUria Pujana, Uxue ORCID
dc.contributor.authorCarrillo Fernández, María Luisa ORCID
dc.contributor.authorVicario Hernando, José Luis ORCID
dc.date.accessioned2022-01-20T18:54:42Z
dc.date.available2022-01-20T18:54:42Z
dc.date.issued2022-01-08
dc.identifier.citationCatalysts 12(1) : (2022) // Article ID 67es_ES
dc.identifier.issn2073-4344
dc.identifier.urihttp://hdl.handle.net/10810/55089
dc.description.abstractAn approximation to the synthesis of several sesquiterpenes from the Guaiane family is described in which the core structure was obtained through a transannular Morita-Baylis-Hillman reaction performed under kinetic resolution. Several manipulations of the obtained MBH adduct have been carried out directed towards the total synthesis of &gamma;-Gurjunene, to the formal synthesis of Clavukerin A, to the synthesis of a non-natural isomer of <i>isoguaiane</i> and to the synthesis of an advanced intermediate in the total synthesis of Palustrol.es_ES
dc.description.sponsorshipThis research was funded by the Spanish Ministerio de Ciencia, Innovación y Universidades (MCIU), grant numbers FEDER-CTQ2017-83633P and FEDER-PID2020-118422-GB-I00 and by the Basque Government, grant number Grupos IT908-16.es_ES
dc.language.isoenges_ES
dc.publisherMDPIes_ES
dc.relationinfo:eu-repo/grantAgreement/MCIU/CTQ2017-83633Pes_ES
dc.relationinfo:eu-repo/grantAgreement/MCIU/PID2020-118422-GB-I00es_ES
dc.rightsinfo:eu-repo/semantics/openAccesses_ES
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/es/
dc.subjectMorita-Baylis-Hillmanes_ES
dc.subjecttransannulares_ES
dc.subjectkinetic resolutiones_ES
dc.subjectsesquiterpenees_ES
dc.subjectphosphinees_ES
dc.subjectcatalysises_ES
dc.subjectnatural productes_ES
dc.subjectPalustroles_ES
dc.subjectClavukerin Aes_ES
dc.subjectguaienees_ES
dc.titleKinetic Resolution in Transannular Morita-Baylis-Hillman Reaction: An Approximation to the Synthesis of Sesquiterpenes from Guaiane Familyes_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.date.updated2022-01-20T15:24:24Z
dc.rights.holder© 2022 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).es_ES
dc.relation.publisherversionhttps://www.mdpi.com/2073-4344/12/1/67es_ES
dc.identifier.doi10.3390/catal12010067
dc.departamentoesQuímica Orgánica e Inorgánica
dc.departamentoeuKimika Organikoa eta Ez-Organikoa


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© 2022 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
Except where otherwise noted, this item's license is described as © 2022 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).