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Kinetic Resolution in Transannular Morita-Baylis-Hillman Reaction: An Approximation to the Synthesis of Sesquiterpenes from Guaiane Family

dc.contributor.authorMato Santamaría, Raquel
dc.contributor.authorManzano, Rubén ORCID
dc.contributor.authorReyes Martín, Efraim
dc.contributor.authorPrieto Aretxabaleta, Liher ORCID
dc.contributor.authorUria Pujana, Uxue ORCID
dc.contributor.authorCarrillo Fernández, María Luisa ORCID
dc.contributor.authorVicario Hernando, José Luis ORCID
dc.date.accessioned2022-01-20T18:54:42Z
dc.date.available2022-01-20T18:54:42Z
dc.date.issued2022-01-08
dc.identifier.citationCatalysts 12(1) : (2022) // Article ID 67es_ES
dc.identifier.issn2073-4344
dc.identifier.urihttp://hdl.handle.net/10810/55089
dc.description.abstractAn approximation to the synthesis of several sesquiterpenes from the Guaiane family is described in which the core structure was obtained through a transannular Morita-Baylis-Hillman reaction performed under kinetic resolution. Several manipulations of the obtained MBH adduct have been carried out directed towards the total synthesis of &gamma;-Gurjunene, to the formal synthesis of Clavukerin A, to the synthesis of a non-natural isomer of <i>isoguaiane</i> and to the synthesis of an advanced intermediate in the total synthesis of Palustrol.es_ES
dc.description.sponsorshipThis research was funded by the Spanish Ministerio de Ciencia, Innovación y Universidades (MCIU), grant numbers FEDER-CTQ2017-83633P and FEDER-PID2020-118422-GB-I00 and by the Basque Government, grant number Grupos IT908-16.es_ES
dc.language.isoenges_ES
dc.publisherMDPIes_ES
dc.relationinfo:eu-repo/grantAgreement/MCIU/CTQ2017-83633Pes_ES
dc.relationinfo:eu-repo/grantAgreement/MCIU/PID2020-118422-GB-I00es_ES
dc.rightsinfo:eu-repo/semantics/openAccesses_ES
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/es/
dc.subjectMorita-Baylis-Hillmanes_ES
dc.subjecttransannulares_ES
dc.subjectkinetic resolutiones_ES
dc.subjectsesquiterpenees_ES
dc.subjectphosphinees_ES
dc.subjectcatalysises_ES
dc.subjectnatural productes_ES
dc.subjectPalustroles_ES
dc.subjectClavukerin Aes_ES
dc.subjectguaienees_ES
dc.titleKinetic Resolution in Transannular Morita-Baylis-Hillman Reaction: An Approximation to the Synthesis of Sesquiterpenes from Guaiane Familyes_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.date.updated2022-01-20T15:24:24Z
dc.rights.holder© 2022 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).es_ES
dc.relation.publisherversionhttps://www.mdpi.com/2073-4344/12/1/67es_ES
dc.identifier.doi10.3390/catal12010067
dc.departamentoesQuímica Orgánica e Inorgánica
dc.departamentoeuKimika Organikoa eta Ez-Organikoa


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© 2022 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
Except where otherwise noted, this item's license is described as © 2022 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).