Kinetic Resolution in Transannular Morita-Baylis-Hillman Reaction: An Approximation to the Synthesis of Sesquiterpenes from Guaiane Family
dc.contributor.author | Mato Santamaría, Raquel | |
dc.contributor.author | Manzano, Rubén | |
dc.contributor.author | Reyes Martín, Efraim | |
dc.contributor.author | Prieto Aretxabaleta, Liher | |
dc.contributor.author | Uria Pujana, Uxue | |
dc.contributor.author | Carrillo Fernández, María Luisa | |
dc.contributor.author | Vicario Hernando, José Luis | |
dc.date.accessioned | 2022-01-20T18:54:42Z | |
dc.date.available | 2022-01-20T18:54:42Z | |
dc.date.issued | 2022-01-08 | |
dc.identifier.citation | Catalysts 12(1) : (2022) // Article ID 67 | es_ES |
dc.identifier.issn | 2073-4344 | |
dc.identifier.uri | http://hdl.handle.net/10810/55089 | |
dc.description.abstract | An approximation to the synthesis of several sesquiterpenes from the Guaiane family is described in which the core structure was obtained through a transannular Morita-Baylis-Hillman reaction performed under kinetic resolution. Several manipulations of the obtained MBH adduct have been carried out directed towards the total synthesis of γ-Gurjunene, to the formal synthesis of Clavukerin A, to the synthesis of a non-natural isomer of <i>isoguaiane</i> and to the synthesis of an advanced intermediate in the total synthesis of Palustrol. | es_ES |
dc.description.sponsorship | This research was funded by the Spanish Ministerio de Ciencia, Innovación y Universidades (MCIU), grant numbers FEDER-CTQ2017-83633P and FEDER-PID2020-118422-GB-I00 and by the Basque Government, grant number Grupos IT908-16. | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | MDPI | es_ES |
dc.relation | info:eu-repo/grantAgreement/MCIU/CTQ2017-83633P | es_ES |
dc.relation | info:eu-repo/grantAgreement/MCIU/PID2020-118422-GB-I00 | es_ES |
dc.rights | info:eu-repo/semantics/openAccess | es_ES |
dc.rights.uri | http://creativecommons.org/licenses/by/3.0/es/ | |
dc.subject | Morita-Baylis-Hillman | es_ES |
dc.subject | transannular | es_ES |
dc.subject | kinetic resolution | es_ES |
dc.subject | sesquiterpene | es_ES |
dc.subject | phosphine | es_ES |
dc.subject | catalysis | es_ES |
dc.subject | natural product | es_ES |
dc.subject | Palustrol | es_ES |
dc.subject | Clavukerin A | es_ES |
dc.subject | guaiene | es_ES |
dc.title | Kinetic Resolution in Transannular Morita-Baylis-Hillman Reaction: An Approximation to the Synthesis of Sesquiterpenes from Guaiane Family | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.date.updated | 2022-01-20T15:24:24Z | |
dc.rights.holder | © 2022 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). | es_ES |
dc.relation.publisherversion | https://www.mdpi.com/2073-4344/12/1/67 | es_ES |
dc.identifier.doi | 10.3390/catal12010067 | |
dc.departamentoes | Química Orgánica e Inorgánica | |
dc.departamentoeu | Kimika Organikoa eta Ez-Organikoa |
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Except where otherwise noted, this item's license is described as © 2022 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).